MedWorm: Chemistry

Synform issue 2010/4

Synthesis — Sat, 20 Mar 2010 15:56:54 +0100

Synthesis 2010; 2010: A33-A38DOI: 10.1055/s-0029-1219633© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.Get connected:Table of contents (Source: Synthesis)

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Selective Synthesis of Allenes and Alkynes through Ligand-Controlled, Palladium-Catalyzed Decarboxylative Hydrogenolysis of Propargylic Formates

Organic Letters — Sat, 20 Mar 2010 10:08:06 +0100

Organic Letters, Volume 0, Issue 0, Articles ASAP (As Soon As Publishable). (Source: Organic Letters)

(Py)2Co(CH2SiMe3)2 As an Easily Accessible Source of “CoR2”

Organometallics — Sat, 20 Mar 2010 10:07:55 +0100

Organometallics, Volume 0, Issue 0, Articles ASAP (As Soon As Publishable). (Source: Organometallics)

Structure of the Ethylammonium Nitrate Surface: An X-ray Reflectivity and Vibrational Sum Frequency Spectroscopy Study

Langmuir — Sat, 20 Mar 2010 10:07:19 +0100

Langmuir, Volume 0, Issue 0, Articles ASAP (As Soon As Publishable). (Source: Langmuir)

Erratum: Length-Dependent Optical Effects in Single Walled Carbon Nanotubes

Journal of Physical Chemistry B — Sat, 20 Mar 2010 10:06:15 +0100

The Journal of Physical Chemistry B, Volume 0, Issue 0, Articles ASAP (As Soon As Publishable). (Source: Journal of Physical Chemistry B)

Modeling the Rovibrationally Excited C2H4OH Radicals from the Photodissociation of 2-Bromoethanol at 193 nm

Journal of Physical Chemistry A — Sat, 20 Mar 2010 10:06:03 +0100

The Journal of Physical Chemistry A, Volume 0, Issue 0, Articles ASAP (As Soon As Publishable). (Source: Journal of Physical Chemistry A)

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Zinc Chloride Promoted Formal Oxidative Coupling of Aromatic Aldehydes and Isocyanides to α-Ketoamides

The Journal of Organic Chemistry — Sat, 20 Mar 2010 10:05:42 +0100

The Journal of Organic Chemistry, Volume 0, Issue 0, Articles ASAP (As Soon As Publishable). (Source: The Journal of Organic Chemistry)

(1S)-1,5-Anhydro-1-[5-(4-ethoxybenzyl)-2-methoxy-4-methylphenyl]-1-thio-d-glucitol (TS-071) is a Potent, Selective Sodium-Dependent Glucose Cotransporter 2 (SGLT2) Inhibitor for Type 2 Diabetes Treatment

Journal of Medicinal Chemistry — Sat, 20 Mar 2010 10:05:20 +0100

Journal of Medicinal Chemistry, Volume 0, Issue 0, Articles ASAP (As Soon As Publishable). (Source: Journal of Medicinal Chemistry)

Bonding in Classical and Nonclassical Transition Metal Carbonyls: The Interacting Quantum Atoms Perspective

Journal of Chemical Theory and Computation — Sat, 20 Mar 2010 10:05:14 +0100

Journal of Chemical Theory and Computation, Volume 0, Issue 0, Articles ASAP (As Soon As Publishable). (Source: Journal of Chemical Theory and Computation)

Enantioselective Alkenylation via Nickel-Catalyzed Cross-Coupling with Organozirconium Reagents

Journal of the American Chemical Society — Sat, 20 Mar 2010 10:03:32 +0100

Journal of the American Chemical Society, Volume 0, Issue 0, Articles ASAP (As Soon As Publishable). (Source: Journal of the American Chemical Society)

Synthesis, Structure, and Electrochemistry of the Dicluster Molecular Pincer [Pt3(μ-PBut2)3(CO)2]2(μ-1′,1′′′-diethynylbiferrocene)

Inorganic Chemistry — Sat, 20 Mar 2010 10:03:04 +0100

Inorganic Chemistry, Volume 0, Issue 0, Articles ASAP (As Soon As Publishable). (Source: Inorganic Chemistry)

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Erratum: Transition Metal-Catalyzed Direct Arylation of Substrates with Activated sp3-Hybridized C−H Bonds and Some of Their Synthetic Equivalents with Aryl Halides or Pseudohalides

Chemical Reviews — Sat, 20 Mar 2010 10:01:56 +0100

Chemical Reviews, Volume 0, Issue 0, Articles ASAP (As Soon As Publishable). (Source: Chemical Reviews)

Kinetics of Chemical Degradation in Monoclonal Antibodies: Relationship between Rates at the Molecular and Peptide Levels

Analytical Chemistry — Sat, 20 Mar 2010 10:01:06 +0100

Analytical Chemistry, Volume 0, Issue 0, Articles ASAP (As Soon As Publishable). (Source: Analytical Chemistry)

This Day in Science History - March 20 - Mayer and Conservation of Energy

About.com Chemistry — Sat, 20 Mar 2010 00:05:11 +0100

March 20th marks the passing of Julius Robert von Mayer. Mayer was a German physician who had a hobby of studying physics. Most of his work centered around how energy was transferred from one form to another. He was one of the first to recognize that plants converted light into chemical energy, and the process of oxidation was the primary source of energy in living creatures. He also outlined the earliest versions of what would become the first law of thermodynamics by writing "Energy is neither created nor destroyed". He attempted to publish his ideas as conservation of force, but had several basic errors due to his lack of formal physics training and was largely ignored. James Joule published his work a year later describing the conservation of energy and mechanical equivalent of heat an...

Savannah's Nuclear Bomb

About.com Chemistry — Sat, 20 Mar 2010 00:00:00 +0100

About.com is holding a meeting in Savannah this weekend so I suspect my coworkers would be interested to know that there is a live nuclear bomb off the Georgia coast. In February 1958 a B-47 bomber on a training mission out of Homestead Air Force Base in Florida had a collision with an F-86. The pilot of the F-86 parachuted to safety and the fighter jet crashed. The B-47 also sustained damage. The crew requested and received permission to jettison the 7,600 pound Mark 15 bomb it was carrying so that the aircraft could more safely land at Hunter Air Force Base. The bomb was lost somewhere in Wassaw Sound off the shores of Tybee Island, where it remains to this day, probably sunk in 5-12 feet of muck at the bottom of the sound. This puts it in shallow water just off the coast of Savannah, cl...

4-Iodoanilinium perchlorate