Journal of Environmental Science and Health. Part. B, Pesticides, Food Contaminants, and Agricultural Wastes
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Food contamination control in European new Member States and associated candidate countries: data collected within the SAFEFOODNET project.
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This paper reports the results obtained from the data collected within the European Commission funded project SAFEFOODNET regarding the state of the art in the control of chemical food contaminants in twelve European New Member States and one Associated Candidate Country (Turkey). Information has been gathered on institutions involved in food chemical contamination control, types of contaminants and matrices analyzed, procedures for data quality assurance, purposes of the analyses and accessibility of data in the participant countries. The resulting picture points out the general availability of adequate capabilities f...
Source: Journal of Environmental Science and Health. Part. B, Pesticides, Food Contaminants, and Agricultural Wastes - May 1, 2009 Category: Environmental Health Authors: Maggioni S, Benfenati E, Colosio C, Moretto A, Roots O, Tasiopoulou S, Visentin S Tags: J Environ Sci Health B Source Type: journals
Effects of nitrocompounds on uric acid-utilizing microorganisms, nitrogen retention, and microbial community in laying hen manure.
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A study was conducted to evaluate effects of nitrocompounds on growth of uric acid-utilizing microorganisms, nitrogen retention, and microbial community in laying hen manure. There were three treatments: control, 100 mM nitropropanol (NPL), and 100 mM nitropropionic acid (NPC). The mixed laying hen manure was divided into 3 groups and incubated at 23 degrees C for 7 days. On Days 0, 3, and 7, samples were collected to measure the quantity of uric acid-utilizing microorganisms, total nitrogen retention, and microbial community changes. Both nitrocompounds significantly reduced growth of the uric acid-utilizing microorga...
Source: Journal of Environmental Science and Health. Part. B, Pesticides, Food Contaminants, and Agricultural Wastes - May 1, 2009 Category: Environmental Health Authors: Kim WK, Weeks LJ, Anderson RC, Nisbet DJ, Dunkley K, Ricke SC Tags: J Environ Sci Health B Source Type: journals
Molecular characterization of soil bacteria antagonistic to Rhizoctonia solani, sheath blight of rice.
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Bacillus pumillus MTCC7615 has been identified as a potent isolate against Rhizocotonia solani, the fungal pathogen causing sheath blight in rice. The study aimed at probing the role of a 23kb size plasmid pJCP07 of Bacillus pumillus MTCC7615 in its fungal antagonism towards Rhizocotonia solani. Plasmid pJCP07 was found to be involved in production of a fungal antagonistic compound as demonstrated by plasmid curing and conjugational transfer experiments. Tn5 insertional studies further confirmed that the plasmid pJCP07 of Bacillus pumillus MTCC7615 carries some of the gene(s) involved in production of compound antagoni...
Source: Journal of Environmental Science and Health. Part. B, Pesticides, Food Contaminants, and Agricultural Wastes - May 1, 2009 Category: Environmental Health Authors: Padaria JC, Singh A Tags: J Environ Sci Health B Source Type: journals
Effectiveness of control strategies against Botrytis cinerea in vineyard and evaluation of the residual fungicide concentrations.
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This investigation was undertaken to test different control strategies against Botrytis cinerea vineyards. Two commercial vineyards, "Barbera" and "Moscato," located in Piedmont (Northern Italy) were divided into seven plots and treated with different combinations of fungicides including fenhexamid, pyrimethanil, fludioxonil + cyprodinil, iprodione, and boscalid, a new carboxamide compound. An integrated strategy including a chemical (pyrimethanil) and a biocontrol agent (Trichoderma spp. t2/4ph1) was also included. At harvest, the percentage of bunches and berries attacked by B. cinerea and the concentration of the ch...
Source: Journal of Environmental Science and Health. Part. B, Pesticides, Food Contaminants, and Agricultural Wastes - May 1, 2009 Category: Environmental Health Authors: Gabriolotto C, Monchiero M, Negre M, Spadaro D, Gullino ML Tags: J Environ Sci Health B Source Type: journals
Bendiocarb effect on liver and central nervous system in the chick embryo.
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The aim of the study was to investigate toxicity of bendiocarb (2, 3-isopropyledene-dioxyphenyl methylcarbamate) to organs of chicken embryo. The toxic action of bendiocarb was observed on liver and central nervous system (CNS). Bendiocarb was administered to chicken embryos at embryonic day (ED) 3 in a dose 500 microg/egg and 10 ED (800 microg/egg). The observations showed no macroscopic or microscopic changes in the liver and CNS with either dose or day of incubation when the bendiocarb was administered. The liver and CNS were also investigated for caspase activity in relation to application of bendiocarb and no diff...
Source: Journal of Environmental Science and Health. Part. B, Pesticides, Food Contaminants, and Agricultural Wastes - May 1, 2009 Category: Environmental Health Authors: Petrovova E, Sedmera D, Lesnik F, Luptakova L Tags: J Environ Sci Health B Source Type: journals
Lethal and sublethal effects of simvastatin, irgarol, and PBDE-47 on the estuarine fish, Fundulus heteroclitus.
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This study investigated the effects of simvastatin, a lipid-regulating drug; irgarol, an antifouling biocide; and PBDE-47, a brominated flame retardant, on the estuarine fish, Fundulus heteroclitus. Sublethal effects (changes in glutathione (GSH), lipid peroxidation (LPx), acetylcholinesterase (AChE), and cholesterol (CHL) levels) and lethal effects (survival) were determined after individual exposure to the three compounds. There were no significant differences in GSH or CHL levels in fish exposed to any of the test compounds. LPx levels significantly decreased with increasing irgarol concentrations. AChE levels were sign...
Source: Journal of Environmental Science and Health. Part. B, Pesticides, Food Contaminants, and Agricultural Wastes - May 1, 2009 Category: Environmental Health Authors: Key PB, Hoguet J, Chung KW, Venturella JJ, Pennington PL, Fulton MH Tags: J Environ Sci Health B Source Type: journals
Chlortetracycline and tylosin runoff from soils treated with antimicrobial containing manure.
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This study assessed the runoff potential of tylosin and chlortetracycline (CTC) from soils treated with manure from swine fed rations containing the highest labeled rate of each chemical. Slurry manures from the swine contained either CTC at 108 microg/g or tylosin at 0.3 microg/g. These manures were surface applied to clay loam, silty clay loam, and silt loam soils at a rate of 0.22 Mg/ha. In one trial, tylosin was applied directly to the soil surface to examine runoff potential of water and chemical when manure was not present. Water was applied using a sprinkler infiltrometer 24-hr after manure application with runoff c...
Source: Journal of Environmental Science and Health. Part. B, Pesticides, Food Contaminants, and Agricultural Wastes - May 1, 2009 Category: Environmental Health Authors: Hoese A, Clay SA, Clay DE, Oswald J, Trooien T, Thaler R, Carlson CG Tags: J Environ Sci Health B Source Type: journals
In vitro toxicity of selected fungicides from the groups of benzimidazoles and demethylation inhibitors to Cladobotryum dendroides and Agaricus bisporus.
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Twenty microfungal isolates were collected from diseased fruiting bodies of Agaricus bisporus sampled from Serbian mushroom farms during 2003-2007. Based on morphological characteristics and pathogenicity tests, the isolates were identified as Cladobotryum dendroides. The isolates of C. dendroides and A. bisporusF56 and U3 were tested for sensitivity to several selected fungicides in vitro. C. dendroides isolates were found to be more sensitive to prochloraz manganese and flusilazole + carbendazim than to the other fungicides tested (EC(50) values were 0.09 and 0.11 mg L(- 1), respectively) and weakly resistant to thio...
Source: Journal of Environmental Science and Health. Part. B, Pesticides, Food Contaminants, and Agricultural Wastes - May 1, 2009 Category: Environmental Health Authors: Potocnik I, Vukojević J, Stajić M, Rekanović E, Milijasević S, Todorović B, Stepanović M Tags: J Environ Sci Health B Source Type: journals
Short- and long-term exposure to low levels of pesticide and flavonoid mixtures modify endogenous antioxidants in tissues of rats.
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The objective of this study was to determine if interaction between phytochemical mixtures and low level exposure to pesticides would modify tissue endogenous antioxidants in rats. Two experiments were conducted using dietary flavonoid (F) and oral pesticide (P) mixtures (FM, PM) on changes in the activities of superoxide dismutase (SOD), glutathione peroxidase (GPX) and glutathione concentrations (GSH) in male Sprague Dawley rats (150-175 g) fed for 2 or 4 weeks the AIN 93M diet with or without equal amounts of quercetin, rutin, catechin (FM) at 1.0 mM or 5 mM/kg diet, and with/without PM fed orally at 0.1 mL/d/5d/wk (PM ...
Source: Journal of Environmental Science and Health. Part. B, Pesticides, Food Contaminants, and Agricultural Wastes - May 1, 2009 Category: Environmental Health Authors: Panemangalore M, Bebe FN Tags: J Environ Sci Health B Source Type: journals
Multiresidue analysis of organochlorine and pyrethroid pesticides in ground beef meat by gas chromatography-mass spectrometry.
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A multiresidue method was developed and optimized for the identification/quantification of organochlorine pesticides (OCPs) and pyrethroids (PYRs) in beef meat samples. Samples extraction was performed by an automated solvent extractor and the extracts were cleaned-up by a tandem-cartridge system consisting of an Extrelut NT3 combined with a Sep-Pack C18 cartridge and a florisil minicartridge. Analysis was finally carried out by gas chromatography coupled with quadrupole mass spectrometry (GC/MS). The performance of the method was investigated in terms of linearity, accuracy, precision, detection limit (LOD) and quanti...
Source: Journal of Environmental Science and Health. Part. B, Pesticides, Food Contaminants, and Agricultural Wastes - May 1, 2009 Category: Environmental Health Authors: Stefanelli P, Santilio A, Cataldi L, Dommarco R Tags: J Environ Sci Health B Source Type: journals
Synthesis and pesticidal activity of new N-alkyl-N-[1-(2-hydroxyphenyl) ethyl]amines.
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A series of novel N-alkyl-N-[1-(2-hydroxyphenyl) ethyl]amines were synthesized as potential new agents to control pests. Their structures were confirmed on the basis of IR, NMR and elemental analyses. Six new N-alkyl-N-[1-(2-hydroxyphenyl) ethyl]amines were prepared by reduction of corresponding Schiff bases using sodium borohydride in 80-87 % yields. These compounds were tested for their antifungal activity against two pathogenic fungi viz., Rhizoctonia bataticola ITCC 0482 and Sclerotium rolfsii ITCC 5226 and for insecticidal activity against insects of stored grain pest Callosobruchus analis. Fungicidal bioassay rev...
Source: Journal of Environmental Science and Health. Part. B, Pesticides, Food Contaminants, and Agricultural Wastes - May 1, 2009 Category: Environmental Health Authors: Shakil NA, Kumar J, Pandey A, Ahluwalia V, Singh MK, Srivastava C Tags: J Environ Sci Health B Source Type: journals
Pendimethalin and oxyfluorfen degradation under two irrigation conditions over four years application.
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A four-year field study was conducted to determine the effect of pluviometric conditions on pendimethalin and oxyfluorfen soil dynamics. Adsorption, dissipation and soil movement were studied in a sandy loam soil from 2003 to 2007. Pendimethalin and oxyfluorfen were applied every year on August at 1.33 and 0.75 kg ha(-1), respectively. Herbicide soil concentrations were determined at 0, 10, 20, 40, 90 and 340 days after application (DAA), under two pluviometric regimens, natural rainfall and irrigated (30 mm every 15 days during the first 90 DAA). More than 74% of the herbicide applied was detected at the top 2.5 cm la...
Source: Journal of Environmental Science and Health. Part. B, Pesticides, Food Contaminants, and Agricultural Wastes - May 1, 2009 Category: Environmental Health Authors: Alister CA, Gomez PA, Rojas S, Kogan M Tags: J Environ Sci Health B Source Type: journals
Dissipation and sorption of six commonly used pesticides in two contrasting soils of New Zealand.
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We investigated dissipation and sorption of atrazine, terbuthylazine, bromacil, diazinon, hexazinone and procymidone in two contrasting New Zealand soils (0-10 cm and 40-50 cm) under controlled laboratory conditions. The six pesticides showed marked differences in their degradation rates in both top- and subsoils, and the estimated DT(50) values for the compounds were: 19-120 (atrazine), 10-36 (terbuthylazine), 12-46 (bromacil), 7-25 (diazinon), 8-92 (hexazinone) and 13-60 days for procymidone. Diazinon had the lowest range for DT(50) values, while bromacil and hexazinone gave the highest DT(50) values under any given ...
Source: Journal of Environmental Science and Health. Part. B, Pesticides, Food Contaminants, and Agricultural Wastes - May 1, 2009 Category: Environmental Health Authors: Sarmah AK, Close ME, Mason NW Tags: J Environ Sci Health B Source Type: journals
Ammonia volatilization loss from surface applied livestock manure.
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Ammonia (NH(3)) emission from livestock manures used in agriculture reduces N uptake by crops and negatively impacts air quality. This laboratory study was conducted to evaluate NH(3)emission from different livestock manures applied to two soils: Candler fins sand (CFS; light-textured soil, pH 6.8 and field capacity soil water content of 70 g kg(-1)) from Lake Alfred, Florida and Ogeechee loamy sand (OLS; medium-textured soil, pH 5.2 and field capacity soil water content of 140 g kg(-1)) from Savannah, Georgia. Poultry litter (PL) collected from a poultry farm near Douglas, Georgia, and fresh solid separate of swine ma...
Source: Journal of Environmental Science and Health. Part. B, Pesticides, Food Contaminants, and Agricultural Wastes - March 1, 2009 Category: Environmental Health Authors: Paramasivam S, Jayaraman K, Wilson TC, Alva AK, Kelson L, Jones LB Tags: J Environ Sci Health B Source Type: journals
Screening Brassica species for glucosinolate content.
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Glucosinolates (GSLs), a group of compounds found in Brassica plants, are toxic to some soil-borne plant pathogens because of the toxicity of their hydrolysis products, isothiocyanates. Other phytochemicals found in Brassica plants, such as phenols and ascorbic acid, may compliment the activity of GSLs. A survey of Brassica accessions from the national germplasm repository was conducted to identify potential cover crops that could be soil-incorporated for use as biofumigants. Ten Brassica accessions that demonstrated relative cold tolerance, rapid maturity, and superior biomass production were selected. The selected ac...
Source: Journal of Environmental Science and Health. Part. B, Pesticides, Food Contaminants, and Agricultural Wastes - March 1, 2009 Category: Environmental Health Authors: Antonious GF, Bomford M, Vincelli P Tags: J Environ Sci Health B Source Type: journals
The use of naturally generated volatile fatty acids for herbicide removal via denitrification.
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This research focuses on the removal of 2, 4-D via denitrification, with a particular emphasis on the effect of adding naturally generated volatile fatty acids (VFAs) as a carbon source. These VFAs had been produced from an acid-phase anaerobic digester (mean VFA concentration of 3153 +/- 801 mg/L [as acetic acid]). The first step involved developing 2, 4-D degrading bacteria in a sequencing batch reactor (SBR) fed with both sewage and 2, 4-D (30-100 mg/L). Subsequent denitrification batch tests demonstrated that the specific denitrification rate increased from 0.0119 +/- 0.0039 to 0.0192 +/- 0.0079 g NO(3)-N/g volatil...
Source: Journal of Environmental Science and Health. Part. B, Pesticides, Food Contaminants, and Agricultural Wastes - March 1, 2009 Category: Environmental Health Authors: He X, Wareham DG Tags: J Environ Sci Health B Source Type: journals
Application of indoxacarb for managing shoot and fruit borer of eggplant (Solanum melongena L.) and its decontamination.
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Indoxacarb was applied at 75 and 150 g a.i. ha(-1) for two years to an eggplant (Solanum melongena L.) crop grown in the field plots in order to evaluate its efficacy for management of the lepidopteron pest, shoot and fruit borer. The residues of the insecticide were quantified by high-pressure liquid chromatography (HPLC). The mean initial deposits of indoxacarb on eggplant fruits were found to be 2.60-2.634 mg kg(-1) and 3.64-3.68 mg kg(-1) from the two rates of applications, respectively. They declined with time and reached to non-detectable (< 0.02 mg kg(-1)) after 15-20 d. Residues dissipated with a half-life o...
Source: Journal of Environmental Science and Health. Part. B, Pesticides, Food Contaminants, and Agricultural Wastes - March 1, 2009 Category: Environmental Health Authors: Saimandir J, Gopal M Tags: J Environ Sci Health B Source Type: journals
The effects of soil and Trifolium repens (white clover) on the fate of estrogen.
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In this study, we investigated the behavior of estrogens in the rhizosphere of white clover (Trifolium repens, clover hereafter) with two different pot tests, using soil and agar as growth media. In a pot test using agar spiked with estrogen, the estrogen concentration in the agar with clover decreased to non-detectable levels within one month, while in the agar without clover, 60% of initially added estrogen remained after one month. The half-lives of estrone (E1) and 17beta -estradiol (E2) in the agar with clover were 2.4-3.8 and 13.2 d, respectively. The dissipation of E1 followed first-order rate law, while that of E2 ...
Source: Journal of Environmental Science and Health. Part. B, Pesticides, Food Contaminants, and Agricultural Wastes - March 1, 2009 Category: Environmental Health Authors: Sakurai S, Fujikawa Y, Kakumoto M, Sugahara M, Hamasaki T, Umeda M, Fukui M Tags: J Environ Sci Health B Source Type: journals
Quantitative structure-activity relationship for the depuration rate constants of polychlorinated biphenyls in the freshwater mussel, Elliptio complanata.
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Partial least squares (PLS) regression together with 16 theoretical molecular structural descriptors was successfully used to develop a quantitative structure-activity relationship (QSAR) model on the depuration rate constants (k(d)) of polychlorinated biphenyls (PCBs) in freshwater mussel Elliptio complanata. The cross validated Q(2)(cum) and the correlation coefficient R for the model is 0.871 and 0.941, respectively. The achievement of satisfactory Q(2)(cum) and R values indicate significant high robustness and good predictive ability of the model. The model was tested as acceptable for prediction of logk(d) (the lo...
Source: Journal of Environmental Science and Health. Part. B, Pesticides, Food Contaminants, and Agricultural Wastes - March 1, 2009 Category: Environmental Health Authors: Xu M, Liu X, Wang L, Wu D, Yang Z, Cui B Tags: J Environ Sci Health B Source Type: journals
Pesticide exposure and blood endosulfan levels after first season spray amongst farm workers in the Western Cape, South Africa.
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The study investigated serum endosulfan changes resulting from occupational exposure to the pesticide on farms. Eight applicators and 17 non-applicators were tested (serum endosulfan, anthropometry, short exposure questionnaire) before and after the first day of seasonal spraying. Task-based job exposure matrix (JEM) estimates were calculated. Mean baseline serum endosulfan (530 +/- 0.05 microg/L) was high. Increases in post-spraying endosulfan levels (IPSE) were higher in applicators (mean = 60 +/- 90 microg/L) than in non-applicators (mean = 3.5 x 10(- 6)+/- 90.0 microg/L) adjusting for age (beta = 54.0, p = 0.162, R...
Source: Journal of Environmental Science and Health. Part. B, Pesticides, Food Contaminants, and Agricultural Wastes - March 1, 2009 Category: Environmental Health Authors: Dalvie MA, Africa A, Solomons A, London L, Brouwer D, Kromhout H Tags: J Environ Sci Health B Source Type: journals
Removal of mixed pesticides from drinking water system by photodegradation using suspended and immobilized TiO2.
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Lindane (1alpha, 2alpha, 3beta, 4alpha, 5alpha, 6beta-hexachloro cyclohexane), methyl parathion (O,O-dimethyl-O-4-nitrophenyl phosphorothioate) and dichlorvos (2,2-dichlorovinyl-O-O-dimethyl phosphate) are removed from water individually and as a mixture by photo degradation using suspended and immobilized forms of TiO(2) (Degussa P-25). Studies were conducted to optimize the coating thickness of immobilized photo catalyst. The rate of degradation of pesticides was compared in both suspended and immobilized TiO(2) systems. Degradation studies of mixed pesticides were carried out with low concentrations (1.0 and 2.5 mg/...
Source: Journal of Environmental Science and Health. Part. B, Pesticides, Food Contaminants, and Agricultural Wastes - March 1, 2009 Category: Environmental Health Authors: Senthilnathan J, Philip L Tags: J Environ Sci Health B Source Type: journals
Transport and deposition of organochlorine pesticides from farmland to estuary under tropical regime and their potential risk to aquatic biota.
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In this study, residues of organochlorine pesticides (OCPs) in water, suspended particulate matter (SPM), sediment and oysters from the Chanthaburi estuary were monitored closely in the wet and dry seasons for determining potential environmental risks. In water samples, out of twenty OCPs measured, endosulfan and hexachlorocyclohexanes (HCHs) were the two predominant compounds ranging and concentrations between 0.6-13 ng/L and 1-12 ng/L, respectively. Both compounds were found in higher concentrations during the wet season. The two insecticides were significantly correlated with total organic carbon (TOC) in the water with...
Source: Journal of Environmental Science and Health. Part. B, Pesticides, Food Contaminants, and Agricultural Wastes - March 1, 2009 Category: Environmental Health Authors: Leadprathom N, Parkpian P, Satayavivad J, Delaune RD, Jugsujinda A Tags: J Environ Sci Health B Source Type: journals
Degradation behavior of sulfadiazine in soils under different conditions.
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This study investigated the degradation of sulfadiazine in three soils and also determined its sorption and hydrolysis behaviors as well. At the spike concentration of 10 mg/kg, the half-lives for sulfadiazine in the aerobic nonsterile soils ranged from 12 days to 18 days. Sulfadiazine was more persistent in the anoxic soils with the half-lives ranging between 57 days and 237 days and soil microorganisms played little role in the dissipation process under anoxic conditions. The decline in sulfadiazine concentrations was also observed in the sterile soils under aerobic conditions. Hydrolysis could not explain this phenomena...
Source: Journal of Environmental Science and Health. Part. B, Pesticides, Food Contaminants, and Agricultural Wastes - March 1, 2009 Category: Environmental Health Authors: Yang JF, Ying GG, Yang LH, Zhao JL, Liu F, Tao R, Yu ZQ, Peng P Tags: J Environ Sci Health B Source Type: journals
Solubility and adsorption behaviors of chlorpyriphos-methyl in the presence of surfactants.
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In the present work changes in the adsorption of the pesticide chlorpyrifos-methyl (CLP-m) on soil colloids induced by application of surfactants were determined using a batch equilibrium method. The surfactants used were sodium dodecyl sulphate (SDS), Tween 20, and dihexadecyldimethylammonium bromide (DHAB). The adsorption isotherms of CLP-m in aqueous medium and in surfactant solutions at concentration equal to the critical micelle concentration (CMC) fitted the Freunlich adsorption equation generally with R(2) values greater than 0.96. While the addition of SDS and DHAB decreased the pesticide adsorption, the additi...
Source: Journal of Environmental Science and Health. Part. B, Pesticides, Food Contaminants, and Agricultural Wastes - March 1, 2009 Category: Environmental Health Authors: Gennari M, Messina C, Abbate C, Baglieri A, Boursier C Tags: J Environ Sci Health B Source Type: journals
Effects of thiobencarb in combinations with molinate and chlorpyrifos on selected soil microbial processes.
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This study showed that, when applied at recommended application rates, TBC, MOL, and CPF (individually or as binary mixtures), had little or only transitory effects on the functional endpoints studied. However, further investigations are needed to assess the effect on microbial densities and community structure despite the low disturbance to the functions noted in this work.
PMID: 19280475 [PubMed - in process]
Source: Journal of Environmental Science and Health. Part. B, Pesticides, Food Contaminants, and Agricultural Wastes - March 1, 2009 Category: Environmental Health Authors: Saison C, Waller NJ, Kumar A, Kookana RS Tags: J Environ Sci Health B Source Type: journals
Removal of fenhexamid and pyrimethanil from aqueous solutions by clays and organoclays.
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The ability of a sodium montmorillonite (CLONa) and two commercial available organoclays having interlayer organic cations possessing different functional groups (CLO20A and CLO30B) was investigated for adsorbing two pesticides namely fenexamid (FEX) and pyrimethanyl (PMT). The two organoclays displayed a higher affinity with the pesticides than the unmodified clay, but the improvement in adsorption capacity varied according to the characteristics of the pesticide and the interlayer organic cation. FEX was adsorbed to a greater extent than PMT by both organoclays, which may be due to the higher hydrophobicity of FEX th...
Source: Journal of Environmental Science and Health. Part. B, Pesticides, Food Contaminants, and Agricultural Wastes - March 1, 2009 Category: Environmental Health Authors: Baglieri A, Borzí D, Abbate C, Négre M, Gennari M Tags: J Environ Sci Health B Source Type: journals
Organo-mineral interactions mask the true sorption potential of biochars in soils.
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The sorption of carbaryl (1-naphthyl methyl carbamate) and ethion [O,O,O',O'-tetraethyl S,S'-methylene bis(phosphorodithioate)] was studied in whole soils as well as after treatment of soil with 2% hydrofluoric acid (HF) to remove paramagnetic materials and to oxidize most forms of labile carbon by photo-oxidation with high energy (UV) on < 53 microm fractions. The sorption coefficient (K(d)) values for carbaryl and ethion in soils did not follow the order of their organic carbon (OC) content, and specially their char content However, the K(oc) values in < 53 microm fractions after hydrofluoric acid/photo-oxidati...
Source: Journal of Environmental Science and Health. Part. B, Pesticides, Food Contaminants, and Agricultural Wastes - March 1, 2009 Category: Environmental Health Authors: Singh N, Kookana RS Tags: J Environ Sci Health B Source Type: journals
Evaluation of a multiresidue method for pesticides in cereals using supercritical fluid extraction and gas chromatographic detection.
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Supercritical fluid extraction (SFE) was evaluated to be applied for residue analysis of 22 gas chromatography/electron capture detector-nitrogen phosphorus detector (GC/ECD-NPD) amenable pesticides in rice, wild rice and wheat. Samples were extracted with supercritical carbon dioxide at 200 atm pressure and 50 degrees C temperature, using methanol as a static modifier. Mean recoveries obtained with the proposed SFE method at two spiking levels with four replicates per level are compared with those obtained with an ethyl acetate-based solvent extraction/gel permeation chromatography (GPC) clean up method. Both methods ...
Source: Journal of Environmental Science and Health. Part. B, Pesticides, Food Contaminants, and Agricultural Wastes - March 1, 2009 Category: Environmental Health Authors: Valverde A, Aguilera A, Rodriguez M, Brotons M Tags: J Environ Sci Health B Source Type: journals
Review of advances in the thin layer chromatography of pesticides: 2006-2008.
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Applications of thin layer chromatography and high performance thin layer chromatography for the separation, detection, qualitative and quantitative determination, and preparatire isolation of pesticides and their metabolites are reviewed for the period from July 1, 2006 to November 1, 2008. Analyses are described for a variety of sample types and pesticide classes. In addition to references on residue and formulation analysis, studies such as pesticide-structure relationships, identification and characterization of plant pesticides, metabolism, degradation, mobility, and lipophilicity are covered. Future prospects for...
Source: Journal of Environmental Science and Health. Part. B, Pesticides, Food Contaminants, and Agricultural Wastes - March 1, 2009 Category: Environmental Health Authors: Sherma J Tags: J Environ Sci Health B Source Type: journals
Toxicity of lindane (gamma-hexachloroxiclohexane) in Sparus aurata, Crassostrea angulata and Scrobicularia plana.
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The purpose of the present study was to research the sublethal and/or lethal effects produced by the exposure of fish and shellfish to the gamma isomer of lindane, gamma-hexachlorocyclohexane (gamma-HCH). The teleostean fish Sparus aurata and the shellfish Crassostrea angulata and Scrobicularia plana, were exposed to 16 micro g/L of lindane for 15 days. Samples of different fish (liver, kidney and gills) and shellfish (gills, gut, digestive gland and mantle) tissues were extracted and processed for histopathological observations. Although mortality was not detected during the bioassay, sublethal effects (histopathologi...
Source: Journal of Environmental Science and Health. Part. B, Pesticides, Food Contaminants, and Agricultural Wastes - January 10, 2009 Category: Environmental Health Authors: Gonzalez De Canales ML, Oliva M, Garrido C Tags: J Environ Sci Health B Source Type: journals
Influence of avian reproduction ecotoxicological endpoints in the assessment of plant protection products.
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The aim of this paper is to examine the statistical relevance of bird species on the endpoints of avian long-term toxicity studies (eggs laid, eggs set, eggs hatching, embryo survivor, 14-day old survivors and eggshell thickness). Data from 561 animals of three different species (Colinus virginianus, Anas platyrynchos and Coturnix coturnix japonica) tested with five different pesticides were analyzed in this study. The substances considered were: Thiamethoxam (EZ-3-(2-chloro-1,3-thiazol-5-ylmethyl)-5-methyl-1,3,5-oxadiazinan-4-ylidene(nitro)amine), Thiacloprid ((Z)-3-(6-chloro-3-pyridylmethyl)-1,3-thiazolidin-2-ylidene...
Source: Journal of Environmental Science and Health. Part. B, Pesticides, Food Contaminants, and Agricultural Wastes - January 10, 2009 Category: Environmental Health Authors: Fernandez-Perea MT, Prados EA, Villajos AN, Prados JL, Baudin JM Tags: J Environ Sci Health B Source Type: journals
The controlled and sustained release of a fungicide from starch and alginate beads.
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This paper describes the synthesis of starch and alginate beads as controlled release formulations. Different formulations of the fungicide, thiram, were prepared by using BaCl(2) and AlCl(3) as crosslinkers. The beads thus formed were characterized by FTIR and swelling studies. Formulation characteristics like entrapment efficiency, bead size, percentage equilibrium swelling have been evaluated. The release studies of the fungicide from the beads were carried out in vitro and in soil columns. The beads prepared with AlCl(3) have shown more swelling as well as the fungicide release in comparison to beads prepared with ...
Source: Journal of Environmental Science and Health. Part. B, Pesticides, Food Contaminants, and Agricultural Wastes - January 10, 2009 Category: Environmental Health Authors: Singh B, Sharma DK, Gupta A Tags: J Environ Sci Health B Source Type: journals
Persistence of the herbicide butachlor in soil after repeated applications and its effects on soil microbial functional diversity.
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Effects of repeated applications of the herbicide butachlor (N-(butoxymethyl)-2-chloro -N-2',6'-dimethyl acetanilide) in soil on its persistence and soil microbial functional diversity were investigated under laboratory conditions. The degradation half-lives of butachlor at the recommended dosage in soil were calculated to be 12.5, 4.5, and 3.2 days for the first, second, and third applications, respectively. Throughout this study, no significant inhibition of the Shannon-Wiener index H' was observed. However, the Simpson index 1/D and McIntosh index U were significantly reduced (P < or = 0.05) during the initial 3 ...
Source: Journal of Environmental Science and Health. Part. B, Pesticides, Food Contaminants, and Agricultural Wastes - January 10, 2009 Category: Environmental Health Authors: Fang H, Yu YL, Wang XG, Chu XQ, Yang XE Tags: J Environ Sci Health B Source Type: journals
Persistence and distribution of pesticide residues in fresh agricultural food consumed in the province of Bologna.
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The presence of pesticide residues in fresh vegetables and fruit have been qualitatively and quantitatively determined at the laboratories of the Regional Agency for Environmental Protection (ARPA), Division of the Province of Bologna. More than 1,700 samples have been tested by routine analyses. The possible risks for consumers have been evaluated by various parameters. The most important ones were: the amount of each residue; the respective ADI (Acceptable Daily Intake) limit; the contemporary presence of different residues; an estimation of the daily intake, based on the amount of fruit and vegetables consumed per p...
Source: Journal of Environmental Science and Health. Part. B, Pesticides, Food Contaminants, and Agricultural Wastes - January 10, 2009 Category: Environmental Health Authors: Girotti S, Ferri EN, Errani E Tags: J Environ Sci Health B Source Type: journals
Evaluation of the field dissipation of fungicides and insecticides used on fruit bearing trees in northern Italy.
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The dissipation of the fungicides captan, cyprodinil, fludioxonil, dithianon, and tebuconazole and of the insecticides chlorpyrifos, fenitrothion, and malathion was studied, following a single treatment of different cultivars of pears, apples, and peaches. The study was conducted in northern Italy, over two successive growing seasons (2004 and 2005). The treatments were performed by the farmers involved, in line with their usual practice. At various time intervals from treatment to harvest, representative samples of fruit were collected and analyzed for pesticide residues. In some cases, concentrations lower than the m...
Source: Journal of Environmental Science and Health. Part. B, Pesticides, Food Contaminants, and Agricultural Wastes - January 10, 2009 Category: Environmental Health Authors: Passarella I, Elia I, Guarino B, Bourlot G, Nègre M Tags: J Environ Sci Health B Source Type: journals
Effect of a subchronic exposure to Simazine on energetic metabolism of common carp (Cyprinus carpio).
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The energetic parameters, such as glycogen, glucose, proteins, lactate and adenosine triphosphate (ATP) content and lactate deshydrogenase (LDH) activity in tissues and blood of carps from simazine (2-chloro-4,6-bis(ethylamino)-s-triazine) contaminated waters were investigated. In order to confirm the field results, a laboratory experiment was designed in which carps were exposed to simazine at the concentration level of 45 micro g. L(- 1) (10-fold of the amount found in natural waters) for 90 days. Fish from a contaminated reservoir showed low glycogen concentrations in hepatopancreas and muscle, while fish in another...
Source: Journal of Environmental Science and Health. Part. B, Pesticides, Food Contaminants, and Agricultural Wastes - January 10, 2009 Category: Environmental Health Authors: Oropesa AL, García-Cambero JP, Soler F Tags: J Environ Sci Health B Source Type: journals
Acute toxic effects of three pesticides on Pseudomonas putida monitored by microcalorimeter.
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A series of calorimetric experiments were performed to investigate the toxic effects of beta-cypermethrin (BCP), bensulfuron-methyl (BSM) and prometryne (PM) on Pseudomonas putida (P. putida). The metabolic action of P. putida on the three pesticides was studied by obtaining power-time curves. The growth of P. putida was inhibited completely in each case when the concentrations of pesticides were up to 80 micro g mL(- 1). The relationships between the inhibitory ratio (k) and doses of contaminants were approximately linear for the three pesticides. The total heat dissipated per milliliter (Q(total)) for the pesticides ...
Source: Journal of Environmental Science and Health. Part. B, Pesticides, Food Contaminants, and Agricultural Wastes - January 10, 2009 Category: Environmental Health Authors: Chen HL, Yao J, Wang F, Bramanti E, Maskow T, Zaray G Tags: J Environ Sci Health B Source Type: journals
Mercaptobenzothiazole-on-gold organic phase biosensor systems: 1. Enhanced organosphosphate pesticide determination.
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This paper reports the construction of the gold/mercaptobenzothiazole/polyaniline/acetylcholinesterase/polyvinylacetate (Au/ MBT/PANI/AChE/PVAc) thick-film biosensor for the determination of certain organophosphate pesticide solutions in selected aqueous organic solvent solutions. The Au/MBT/PANI/AChE/PVAc electrocatalytic biosensor device was constructed by encapsulating acetylcholinesterase (AChE) enzyme in the PANI polymer composite, followed by the coating of poly(vinyl acetate) (PVAc) on top to secure the biosensor film from disintegration in the organic solvents evaluated. The electroactive substrate called acety...
Source: Journal of Environmental Science and Health. Part. B, Pesticides, Food Contaminants, and Agricultural Wastes - January 10, 2009 Category: Environmental Health Authors: Somerset V, Baker P, Iwuoha E Tags: J Environ Sci Health B Source Type: journals
Pungency in Capsicum chinense: variation among countries of origin.
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The objectives of the present investigation were: (i) to quantify the major capsaicinoids (capsaicin and dihydrocapsaicin) in fruits of Capsicum chinense accessions and (ii) to identify accessions containing great concentrations of capsaicinoids among countries of hot pepper origin. Seeds of C. chinense accessions received from Belize, Brazil, Colombia, Ecuador, Mexico, Peru, Puerto Rico, and United States were field grown in a silty-loam soil. Mature fruits were analyzed for major capsaicinoids content. Capsaicin concentrations were generally greater than dihydrocapsaicin. Fruits of C. chinense accession PI640900 (USA) co...
Source: Journal of Environmental Science and Health. Part. B, Pesticides, Food Contaminants, and Agricultural Wastes - January 10, 2009 Category: Environmental Health Authors: Antonious GF, Berke T, Jarret RL Tags: J Environ Sci Health B Source Type: journals
Nutrient release from fish silage using microwave-enhanced advanced oxidation process.
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The microwave-enhanced advanced oxidation process was used to treat fish silage for nutrient release and solids reduction prior to its use as a fertilizer for greenhouse operations. Fifteen sets of experiments with varying hydrogen peroxide dosages and treatment temperatures were conducted to evaluate the effectiveness of the process on the solubilization of fertilizer constituents. It was found that up to 26% of total Kjeldahl nitrogen could be released as ammonia with 6% hydrogen peroxide dosage at 170 degrees C. An increase of nitrate/nitrite concentration was observed with higher hydrogen peroxide dosage and higher...
Source: Journal of Environmental Science and Health. Part. B, Pesticides, Food Contaminants, and Agricultural Wastes - January 10, 2009 Category: Environmental Health Authors: Chan WI, Lo KV, Liao PH Tags: J Environ Sci Health B Source Type: journals
Level and fate of chlorpropham in potatoes during storage and processing.
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The objective of the present study was to establish the total chlorpropham residue balance (residues in unwashed and washed whole tubers, peeled tubers, peels, boiled and pureed tubers, and washing and cooking waters) for two potato varieties after uniform application as a function of storage time under different typical storage conditions (in a basement, storehouse, and refrigerator) in Lithuania. Chlorpropham concentration on washed and unwashed tubers decreased from approximately 15 mg kg(- 1) after storage for 28 d to approximately 9 mg kg(- 1) after storage for 85 d. Peel concentrations decreased from approximately 50...
Source: Journal of Environmental Science and Health. Part. B, Pesticides, Food Contaminants, and Agricultural Wastes - December 18, 2008 Category: Environmental Health Authors: Sakaliene O, Koskinen WC, Blazauskiene G, Petroviene I Tags: J Environ Sci Health B Source Type: journals
Sorption and photodegradation of chlorpyrifos on riparian and aquatic macrophytes.
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Surface water bodies may become contaminated via spray drift following pesticide application. In this investigation, the photodegradation and sorption of chlorpyrifos was studied in four riparian macrophytes representative of Mediterranean flora (Phragmites australis, Iris pseudacorus, Equisetum pratense and Typha latifolia). The results of experiments with both the active ingredient and the formulation DURSBAN 48(R) EC confirm the ability of these species to interact with chemicals such as chlorpyrifos. The maximum sorption of chlorpyrifos at equilibrium was observed in Phragmites australis (22%). And, the maximum ins...
Source: Journal of Environmental Science and Health. Part. B, Pesticides, Food Contaminants, and Agricultural Wastes - December 18, 2008 Category: Environmental Health Authors: Munoz AR, Trevisan M, Capri E Tags: J Environ Sci Health B Source Type: journals
Effect of insecticide fenamiphos on soil microbial activities in Australian and Ecuadorean soils.
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This study suggests that fenamiphos is likely to be detrimental to nitrification at field application rates.
PMID: 19089710 [PubMed - in process]
Source: Journal of Environmental Science and Health. Part. B, Pesticides, Food Contaminants, and Agricultural Wastes - December 18, 2008 Category: Environmental Health Authors: Caceres TP, He W, Megharaj M, Naidu R Tags: J Environ Sci Health B Source Type: journals
Biodegradation of mixed pesticides by mixed pesticide enriched cultures.
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This paper discusses the degradation kinetics of mixed (lindane, methyl parathion and carbofuran) pesticides by mixed pesticide enriched cultures (MEC) under various environmental conditions. The bacterial strains isolated from the mixed microbial consortium were identified as Pseudomonas aeruginosa (MTCC 9236), Bacillus sp. (MTCC 9235) and Chryseobacterium joostei (MTCC 9237). Batch studies were conducted to estimate the biokinetic parameters like the maximum specific growth rate (mu(max)), Yield Coefficient (Y(T)), half saturation concentration (K(s)) and inhibition concentration (Ki) for individual and mixed pestici...
Source: Journal of Environmental Science and Health. Part. B, Pesticides, Food Contaminants, and Agricultural Wastes - December 18, 2008 Category: Environmental Health Authors: Krishna KR, Philip L Tags: J Environ Sci Health B Source Type: journals
Leaching of Diuron, Linuron and their main metabolites in undisturbed field lysimeters.
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The increasing use of pesticides in Morocco raises the potential risk of groundwater contamination, notably in the Gharb area, which has a shallow groundwater table. Thus, the leaching of two phenyl-ureas, diuron and linuron and their metabolites through undisturbed soil columns was studied under outdoor conditions. The soil chosen is a loamy clay soil, representative of the Gharb agricultural area. After four irrigation events were applied from 31/03/2005 to 15/05/2005, leachates contained higher amounts of linuron (from 0.08% to 6.96% of applied linuron) than diuron (from 0% to 0.27%). The greater mobility of linuron...
Source: Journal of Environmental Science and Health. Part. B, Pesticides, Food Contaminants, and Agricultural Wastes - December 18, 2008 Category: Environmental Health Authors: Imache AE, Dahchour A, Elamrani B, Dousset S, Pozzonni F, Guzzella L Tags: J Environ Sci Health B Source Type: journals
Acute and chronic toxicity of organophosphate monocrotophos to Daphnia magna.
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The acute and chronic toxicity of monocrotophos (MCP), the binary joint toxicity of MCP and bifenthrin (BF), and sodium dodecyl benzene sulfonate (SDBS) to Daphnia magna (D. magna) was evaluated. The 24 h-median effective concentration (24 h-EC(50)) and 48 h-median lethal concentration (48 h-LC(50)) of MCP towards D. magna were 161 and 388 mu g/L, respectively. In addition, the lowest-observed effective concentration (LOEC) and non-observed effective concentration (NOEC) of MCP to D. magna were 10 and 5 mu g/L, respectively. Furthermore, the chronic value (ChV) of MCP against D. magna was 7 mu g/L and the acute chronic...
Source: Journal of Environmental Science and Health. Part. B, Pesticides, Food Contaminants, and Agricultural Wastes - December 18, 2008 Category: Environmental Health Authors: Wang L, Ye W, Zhou S, Lin K, Zhao M, Liu W Tags: J Environ Sci Health B Source Type: journals
Oxidative stress and structure-activity relationship in the zebrafish (Danio rerio) under exposure to paclobutrazol.
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The acute toxicity and changes in the activity of antioxidant enzymes including superoxide dismutase (SOD) and catalase (CAT) in the zebrafish Danio rerio were measured when the fish was exposed to paclobutrazol (PBZ) under laboratory conditions. The median lethal concentration value at 96 h post-exposure (LC(50) (96 h)) was determined to be 20.55 mg/L. In addition, the SOD activities in D. rerio were significantly higher at 96 h post-exposure among the various concentrations of the pollutant tested. The change of CAT activity could be considered as a sensitive biomarker of the oxidative stress induced by PBZ. The stru...
Source: Journal of Environmental Science and Health. Part. B, Pesticides, Food Contaminants, and Agricultural Wastes - December 18, 2008 Category: Environmental Health Authors: Ding F, Song WH, Guo J, Gao ML, Hu WX Tags: J Environ Sci Health B Source Type: journals
Evaluation of the fate of the active ingredients of insecticide sprays used indoors.
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The fate of the active ingredients of insecticide sprays after use in indoor environments was investigated. Indoor air sampling was performed through two types of adsorbents, namely, TENAX TA and XAD-2 (10 L). After sampling, both adsorbents were ultrasonically extracted and analyzed by Gas Chromatography coupled to Mass Spectroscopy. The separation and analysis of the selected compounds were satisfactory and fast (duration of the chromatographic run: 40 min). The method was linear for all examined chemicals over the tested range (2 to 50 ng of absolute compound); limits of detection ranged from 0.42 to 1.32 ng of abso...
Source: Journal of Environmental Science and Health. Part. B, Pesticides, Food Contaminants, and Agricultural Wastes - December 18, 2008 Category: Environmental Health Authors: Leva P, Katsoyiannis A, Barrero-Morero J, Kephalopoulos S, Kotzias D Tags: J Environ Sci Health B Source Type: journals
Multiresidue method for high-performance liquid chromatography determination of carbamate pesticides residues in tea samples.
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A multiresidue method was developed to determine 19 carbamate pesticides in tea samples. Optimizations of different parameters, such as the type of extraction solvents, clean-up cartridges, and elution solvents were carried out. The developed method used acetonitrile as extraction solvent, amino cartridge for adsorbents and acetone-n-hexane as the eluting solution. Nineteen carbamate residues were then analyzed by high-pressure liquid chromatography (HPLC) with fluorescence detector. The present results showed good linearity by correlation coefficients of more than 0.9999 for all analyses. Limits of detection and quant...
Source: Journal of Environmental Science and Health. Part. B, Pesticides, Food Contaminants, and Agricultural Wastes - December 18, 2008 Category: Environmental Health Authors: Wu CC, Chu C, Wang YS, Lur HS Tags: J Environ Sci Health B Source Type: journals
Comparative study of accessibility of distinctive pesticides.
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Interactions of micro-contaminants with soil may play a crucial role in their environmental fate and possible harmful effects. Major goals of our investigations were to model the availability of widely used pesticides and characterize adsorption capabilities of distinctive soil types by the accomplishment of extensive comparative studies and application of several extraction methods. Environmental and biological relevance of these examinations is enhanced by the fact that intrinsic features and specific details of pesticide accessibility have not been revealed so far by a comparative approach. Five different experiment...
Source: Journal of Environmental Science and Health. Part. B, Pesticides, Food Contaminants, and Agricultural Wastes - December 18, 2008 Category: Environmental Health Authors: Virag D, Kiss A Tags: J Environ Sci Health B Source Type: journals
