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Synthesis and proton-conductive behaviour of two MOFs with covalently bonded imidazoles in the channels
Dalton Trans., 2024, Accepted Manuscript DOI: 10.1039/D3DT04338J, PaperKun-Peng Chen, Yue Ma, Hong-Xia Ren, Chenxi Zhang, Qing-Lun Wang Immobilization of imidazole molecules as the proton carriers into MOFs to facilitate the proton conduction is a general strategy for developing high proton conductive materials. Here in, we designed two... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - April 25, 2024 Category: Chemistry Authors: Kun-Peng Chen Source Type: research

Molecular Two-Point Recognition of Fructosyl Valine and Fructosyl Glycyl Histidine in Water by Fluorescent Zn(II)-Terpyridine Complexes Bearing Boronic Acids
This article is licensed under aCreative Commons Attribution-NonCommercial 3.0 Unported Licence.Mar ía Karina Salomón-Flores, Josue Valdes-García, Alejandro O. Viviano-Posadas, Diego Martínez-Otero, Joaquín Barroso-Flores, Iván J. Bazany-Rodríguez, Alejandro Dorazco-González Selective recognition in water of fructosyl amino acids by arylboronic acid-based receptors is a central field of modern supramolecular chemistry that impacts biological and medicinal chemistry. Fructosyl valine (FV) and... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - April 24, 2024 Category: Chemistry Authors: Mar ía Karina Salomón-Flores Source Type: research

Electrochemical water oxidation reaction by dinuclear Re(V) oxo complexes with a 1,4-benzoquinone core via the redox induced electron transfer (RIET) process
Dalton Trans., 2024, Advance Article DOI: 10.1039/D4DT00057A, PaperUday Shee, Debopam Sinha, Sandip Mondal, Kajal Krishna Rajak [ReV(O)(Cl)3(L2−)ReV(O)(Cl)3][NBu4]2 (1, L2− = dianionic 2,5-dihydroxy 1,4-benzoquinone (DBQ2−)) and (2, L2− = dianionic chloranilic acid (CA2−) ligands), as homogeneous electrocatalysts for water oxidation. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - April 24, 2024 Category: Chemistry Authors: Uday Shee Source Type: research

Factors governing the protonation of Keggin-type polyoxometalates: influence of the core structure in clusters
This article is licensed under aCreative Commons Attribution-NonCommercial 3.0 Unported Licence.Hiroshi Sampei, Hiromu Akiyama, Koki Saegusa, Masahiro Yamaguchi, Shuhei Ogo, Hiromi Nakai, Tadaharu Ueda, Yasushi Sekine DFT calculation of Keggin-type polyoxometalates provided the first protonation sites and HOMO-LUMO gaps related to their total charge and bond valence. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - April 24, 2024 Category: Chemistry Authors: Hiroshi Sampei Source Type: research

Aggregation-induced enhanced fluorescence emission of chiral Zn(II) complexes coordinated by Schiff-base type binaphthyl ligands
Dalton Trans., 2024, Accepted Manuscript DOI: 10.1039/D4DT00903G, PaperDaiki Tauchi, Katsuya Kanno, Masashi Hasegawa, Yasuhiro Mazaki, Kazunori Tsubaki, Ken-ichi Sugiura, Takuya Shiga, Seiji Mori, Hiroyuki Nishikawa A pair of novel chiral Zn(II) complexes coordinated by Schiff-base type ligands derived from BINOL (1,1 ’-bi-2-naphthol),R-/S-Zn, were synthesized. X-ray crystallography revealed the presence of two crystallographically independent complexes; one... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - April 24, 2024 Category: Chemistry Authors: Daiki Tauchi Source Type: research

Control of the geometry and anisotropy driven by the combination of steric and anion coordination effects in CoII complexes with N6-tripodal ligands: The impact of the size of the ligand on the magnetization relaxation time
This article is licensed under aCreative Commons Attribution-NonCommercial 3.0 Unported Licence.Aritz Landart Gereka, Mar ía Mar Quesada-Moreno, Maria A. Palacios, Yanling Li, Mykhaylo Ozerov, Jurek Krzystek, Enrique Colacio Four mononuclear CoII complexes of formula [[Co(L)(SCN)2(H2O)0.5(CH3OH)0.5] ·1.5H2O·0.75CH3OH (1), [Co(L1)Cl2]·H2O·2CH3CN (2), [Co(L1)(SCN)2]· 1.5H2O·CH3OH (3) and [Co(L1)]ClO4·2CH3OH (4) were prepared from the N6-tripodal Schiff bases ligands (S)P[N(Me)N=C(H)2-Q]3 (L) and (S)P[N(Me)N=C(H)1-ISOQ]3 (L1), where... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalt...
Source: RSC - Dalton Trans. latest articles - April 24, 2024 Category: Chemistry Authors: Aritz Landart Gereka Source Type: research

Correction: Simple synthetic access to [Au(IBiox)Cl] complexes
This article is licensed under aCreative Commons Attribution 3.0 Unported Licence.Ekaterina A. Martynova, Marco Zuccarello, Domenic Kronenberg, Marek Beli š, Agnieszka Czapik, Ziyun Zhang, Kristof Van Hecke, Marcin Kwit, Olivier Baudoin, Luigi Cavallo, Steven P. Nolan To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - April 24, 2024 Category: Chemistry Authors: Ekaterina A. Martynova Source Type: research

The post-synthesis modification (PSM) of MOFs for catalysis
Dalton Trans., 2024, Advance Article DOI: 10.1039/D4DT00514G, FrontierTendai Gadzikwa, Pricilla Matseketsa The covalent, post-synthesis modification of metal –organic frameworks is an efficient strategy for producing complex pore environments, bringing us closer to the goal of constructing enzyme-like catalysts. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - April 24, 2024 Category: Chemistry Authors: Tendai Gadzikwa Source Type: research

Comprehension of the photoinduced charge transfer assisted energy transfer in Gd3+-based host sensitized tellurate phosphors for thermal sensing and anticounterfeiting labels
Dalton Trans., 2024, Advance Article DOI: 10.1039/D4DT00259H, PaperBhagyalekshmi G.L., Subodh Ganesanpotti Eu3+ activated Ba2Gd2/3TeO6 phosphor exhibits reddish orange luminescence due to the combined charge transfer assisted energy transfer from the Gd3+ ion. This phosphor finds applications in optical thermometry and anticounterfeiting. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - April 24, 2024 Category: Chemistry Authors: Bhagyalekshmi G.L. Source Type: research

Evolution of Mn –Bi2O3 from the Mn-doped Bi3O4Br electro(pre)catalyst during the oxygen evolution reaction
Dalton Trans., 2024, Advance Article DOI: 10.1039/D4DT00633J, PaperAvinava Kundu, Ashish Kumar Dhillon, Ruchi Singh, Sanmitra Barman, Soumik Siddhanta, Biswarup Chakraborty Bi3O4Br appears to be nearly inactive for the alkaline oxygen evolution reaction while MnII doping into Bi3O4Br alters its electronic structure and makes it OER active. Mn –Bi2O3 evolves as the reactive species from the Mn –Bi3O4Br pre-catalyst. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - April 24, 2024 Category: Chemistry Authors: Avinava Kundu Source Type: research

Rotational order –disorder and spin crossover behaviour in a neutral iron(II) complex based on asymmetrically substituted large planar ionogenic ligand
This article is licensed under aCreative Commons Attribution 3.0 Unported Licence.Maksym Seredyuk, Kateryna Znovjyak, Francisco Javier Valverde-Mu ñoz, M. Carmen Muñoz, Igor O. Fritsky, José Antonio Real Room temperature spin crossover behaviour and LIESST effect synchronised with order –disorder at the 2-fluorophenyl substituent in a new neutral mononuclear FeII complex based on an asymmetric ionogenic tridentate planar ligand. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - April 24, 2024 Category: Chemistry Authors: Maksym Seredyuk Source Type: research

Design and performance analysis of a mid-infrared broadband thermally tunable metamaterial absorption device based on the phase-change effect
Dalton Trans., 2024, Advance Article DOI: 10.1039/D4DT00657G, PaperTianquan Feng, Chenyu Gong, Shiri Liang, Zao Yi, Yuxuan Yi, Can Ma A mid-infrared broadband thermal tunable absorption device based on phase change material VO2 is proposed. The device can cover the far infrared window, with an average absorption rate higher than 90%, and is polarization independent and insensitive to large incident angle. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - April 24, 2024 Category: Chemistry Authors: Tianquan Feng Source Type: research

A sustainable strategic approach for N-alkylation of amines with activation of alcohols triggered via hydrogen auto-transfer reaction using Pd(II) complex: Evidences for metal-ligand cooperativity
Dalton Trans., 2024, Accepted Manuscript DOI: 10.1039/D4DT00864B, PaperVirendra Kumar Chaudhary, Prashant Kukreti, Keshav Sharma, Kapil Kumar, Sain Singh, Sheela Kumari, Kaushik Ghosh This work describes a new well-defined, air-stable, phosphine free palladium(II) [Pd(L)Cl] (1) catalyst. This catalyst was utilized for N-alkylation of amines and indole synthesis where H2O was found to be... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - April 24, 2024 Category: Chemistry Authors: Virendra Kumar Chaudhary Source Type: research

CdS QDs grown on ellipsoidal BiVO4 for efficient photocatalytic degradation of tetracycline
Dalton Trans., 2024, Advance Article DOI: 10.1039/D4DT00586D, PaperKai Liu, Mao-Jin Ran, Zhi-Rong Li, Yi-Fu Huang, Ze-Yu Jiang, Wan-Ying Li, Shokir Khojiev, Zhi-Yi Hu, Li-Hua Chen, Jing Liu, Yu Li, Bao-Lian Su Designing efficient, inexpensive, and stable photocatalysts to degrade organic pollutants and antibiotics has become an effective way for environmental remediation. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - April 23, 2024 Category: Chemistry Authors: Kai Liu Source Type: research

Magnetic properties and magnetocaloric effect of Ln = Dy, Tb carborane-based metal –organic frameworks
This article is licensed under aCreative Commons Attribution-NonCommercial 3.0 Unported Licence.Zhen Li, Ana Arauzo, Jos é Giner Planas, Elena Bartolomé We report the synthesis, structure and magneto-thermal properties of two isostructural carborane-based MOFs, {[(Ln)3(mCB-L)4(NO3)(DMF)n] ·Solv} with Ln = Dy or Tb, characterized by combining dc and ac magnetometry, XAS-XMCD and heat capacity measurements. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - April 23, 2024 Category: Chemistry Authors: Zhen Li Source Type: research