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Ag(I)-Catalyzed Dearomatizing Spirocyclization/Nucleophile Addition Cascade Reactions of Indole-tethered Ynones
Chem. Commun., 2023, Accepted Manuscript DOI: 10.1039/D3CC03543C, CommunicationDebojyoti Bag, Sanghapal D. Sawant Ag(I)-catalyzed highly diastereoselective construction of divergent spiroindolines is disclosed herein. The approach proceeds via dearomatizing spirocyclization of indole-tethered ynones followed by C-nucleophile or hydride trapping. The established strategy is accompanied... The content of this RSS Feed (c) The Royal Society of Chemistry
Source: RSC - Chem. Commun. latest articles - September 22, 2023 Category: Chemistry Authors: Debojyoti Bag Source Type: research

BF3-Et2O Promoted Bifunctionalization of Aldehydes for the Synthesis of Arylmethyl Substituted Organophosphorus Compounds
Chem. Commun., 2023, Accepted Manuscript DOI: 10.1039/D3CC03898J, CommunicationSajjad Ahmed, Zoya Shafeeq, Feroze Hussain, Qazi Naveed Ahmed A simple and efficient protocol for the synthesis of arylmethyl substituted organophosphorus compounds is presented. This method involves the reaction of diphenyl phosphite with aldehydes in the presence of BF3-Et2O.... The content of this RSS Feed (c) The Royal Society of Chemistry
Source: RSC - Chem. Commun. latest articles - September 22, 2023 Category: Chemistry Authors: Sajjad Ahmed Source Type: research

Atomically dispersed Fe –O4–C sites as efficient electrocatalysts for electrosynthesis of hydrogen peroxide
Chem. Commun., 2023, Advance Article DOI: 10.1039/D3CC03969B, CommunicationLiuyue Cao, Hongrui Wang, Ningyan Cheng, Lei Zhang, Meiqing Shi, Bin-Wei Zhang The SA Fe/GO with Fe –O4–C active sites is developed as an efficient electrocatalyst to enhance the kinetics and selectivity towards the 2e ORR for the electrosynthesis of H2O2. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Source: RSC - Chem. Commun. latest articles - September 22, 2023 Category: Chemistry Authors: Liuyue Cao Source Type: research

Li+ mobility powered by a crystal compound for fast Li –S chemistry
Chem. Commun., 2023, Advance Article DOI: 10.1039/D3CC03535B, CommunicationBen Chen, Boxin Li, Jingxuan Bi, Hongfang Du, Siying Wang, Lei Liu, Linghai Xie, Jinmeng Sun, Zhuzhu Du, Wei Ai A Li-based crystal composited with carbon (LiPN2@C) has been synthesized by a one-step annealing of Li+ absorbed melamine polyphosphate, which presents strong LiPS adsorption and fast Li+ transport for a Li2S cathode. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Source: RSC - Chem. Commun. latest articles - September 22, 2023 Category: Chemistry Authors: Ben Chen Source Type: research

Constructing pyrene-based dimer in a crystal by adjusting steric hindrance over the pyrene plane
CrystEngComm, 2023, Accepted Manuscript DOI: 10.1039/D3CE00744H, PaperZhou-An Xia, Xiangyu Zhang, Chang Xi, Qing Bai, Haichao Liu, Shitong Zhang, Bing Yang Structure –property relationship is always a focus while organic light-emitting materials are used mainly in aggregate state in some fields, such as optoelectronic devices, sensors, and bioimaging. To clarify a clear... The content of this RSS Feed (c) The Royal Society of Chemistry
Source: RSC - CrystEngComm latest articles - September 22, 2023 Category: Chemistry Authors: Zhou-An Xia Source Type: research

Nanostructuring and stabilization of metastable rock-salt ZnO: Impact of high-pressure media and compression geometry
CrystEngComm, 2023, Accepted Manuscript DOI: 10.1039/D3CE00814B, PaperPetr S. Sokolov, Alexandre Courac, Vladimir L. Solozhenko For complete and reproducible recovery of a high-pressure polymorph of zinc oxide, rock-salt ZnO (rs-ZnO), nanostructured wurtzite ZnO (w-ZnO) is typically used as a precursor for high-pressure synthesis. In the... The content of this RSS Feed (c) The Royal Society of Chemistry
Source: RSC - CrystEngComm latest articles - September 22, 2023 Category: Chemistry Authors: Petr S. Sokolov Source Type: research

Fe-modulated NH2 –CoFe MOF nanosheet arrays on nickel foam by cation exchange reaction for an efficient OER electrocatalyst at high current density in alkaline water/seawater
CrystEngComm, 2023, Advance Article DOI: 10.1039/D3CE00728F, PaperDong Hyun Kim, Juyoung Moon, So Yeon Lee, Hyun Ji An, Hayeon Jeong, Jung Tae Park Preparation of NH2–CoFe MOF for the OER in alkaline water/seawater. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Source: RSC - CrystEngComm latest articles - September 22, 2023 Category: Chemistry Authors: Dong Hyun Kim Source Type: research

Saving lives, preventing health risks and restoring health care services in the aftermath of ...
Tripoli, Libya, 22 September 2023 – In the wake of catastrophic floods that had a devastating impact on Libya's east coast, the World Health Organization (WHO) is taking swift action to assist affected communities. WHO is supporting urgent efforts to restore access to health care and control the spread of infectious diseases, especially among the tens of thousands of people who have been displaced and are now living in shelters. “The magnitude of this catastrophe is staggering,” said Dr Ahmed Zouiten, WHO Representative in Libya. “The need for swift, unified action cannot be overstated. We are collaborating closel...
Source: WHO EMRO News - September 22, 2023 Category: Middle East Health Source Type: news

Second-line tests in the differential diagnosis of neoplastic and non-neoplastic hypercortisolism: a systematic review and meta-analysis
DiscussionBoth Dex-CRH and Desmopressin tests can be valid tools in helping discrimination between NNH/pCS and CS. Further studies are needed on this topic, possibly focusing on mild Cushing ’s Disease and well-characterized NNH/pCS patients.Systematic review registrationhttps://www.crd.york.ac.uk/prospero/display_record.php?ID=CRD42022359774, identifier CRD42022359774.
Source: Journal of Endocrinological Investigation - September 22, 2023 Category: Endocrinology Source Type: research

Oxytocin treatment for core symptoms in children with autism spectrum disorder: a systematic review and meta-analysis
ConclusionWhile the therapeutic value of oxytocin in treating core symptoms of ASD in children is not fully established, the results of this meta-analysis indicate a potential moderate effect. However, further studies with larger sample sizes and more robust RCTs are needed to directly demonstrate the efficacy of oxytocin. Future research should also focus on effect size and outcome evaluation accuracy while minimizing bias in RCT experiments.
Source: European Journal of Clinical Pharmacology - September 22, 2023 Category: Drugs & Pharmacology Source Type: research

LABA/LAMA versus LABA/ICS fixed-dose combinations in the prevention of COPD exacerbations: a modeling analysis of literature aggregate data
ConclusionsThis study showed that not all LABA/LAMA FDCs were superior to LABA/ICS FDCs in safety and in preventing moderate or severe exacerbations in patients with stable COPD, providing important quantitative information for COPD-related guidelines.
Source: European Journal of Clinical Pharmacology - September 22, 2023 Category: Drugs & Pharmacology Source Type: research

Dipeptidyl-peptidase-4 inhibitors have anti-inflammatory effects in patients with type 2 diabetes
ConclusionThis meta-analysis demonstrated that DPP-4 inhibitors can significantly attenuate low-grade inflammatory state in patients with T2DM. In addition to improving glycemic control, DDP-4 inhibitors might offer extra therapeutic value by controlling inflammation.Graphical Abstract
Source: European Journal of Clinical Pharmacology - September 22, 2023 Category: Drugs & Pharmacology Source Type: research

Impact of tofogliflozin on hepatic outcomes: a systematic review
ConclusionOverall, an improvement in levels of hepatic parameters was observed in T2DM patients with concurrent liver disorders. However, a large number of clinical trials are needed to prove the efficacy of tofogliflozin on hepatic outcomes in patients with T2DM.
Source: European Journal of Clinical Pharmacology - September 22, 2023 Category: Drugs & Pharmacology Source Type: research

James Webb Telescope finds key ingredient for life in Jupiter ' s moon ocean
Jupiter's icy moon, Europa, may contain carbon, a key ingredient for life, data collected by NASA's James Webb Space Telescope (JWST) has revealed. Europa, the sixth-largest moon in the solar system, is one of the most-promising worlds in the search for life outside our planet. The evidence…#jupiter #europa #nasa #science #samanthatrumbo #cornelluniversity #ithaca #galileo #jwst #tararegio
Source: Reuters: Health - September 22, 2023 Category: Consumer Health News Source Type: news

Why Google ’s Elizabeth Reid isn’t rushing AI search
Generative AI answers are coming to Google, but don’t expect a drastic change. As the head of Google’s core search experience, Elizabeth Reid has a lot going on right now. Read Full Story#google #elizabethreid #readfullstory
Source: Reuters: Health - September 22, 2023 Category: Consumer Health News Source Type: news