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Advanced electrocatalytic redox processes for environmental remediation of halogenated organic water pollutants
This article is licensed under aCreative Commons Attribution 3.0 Unported Licence.Madeleine K. Wilsey, Teona Taseska, Ziyi Meng, Wanqing Yu, Astrid M. M üller An urgent need for quantitative mechanistic understanding of advanced redox processes for aqueous electrocatalytic organohalogen destruction methods is addressed, highlighting remediation of fluorinated, chlorinated, and brominated water pollutants. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Source: RSC - Chem. Commun. latest articles - September 22, 2023 Category: Chemistry Authors: Madeleine K. Wilsey Source Type: research

Not in black or white, encryption of grayscale images by donor-acceptor Stenhouse adducts
Chem. Commun., 2023, Accepted Manuscript DOI: 10.1039/D3CC04098D, CommunicationFanxi Sun, Ang Gao, Xiaoyu Xiong, Yongli Duan, Dacheng Dai, Yifei Zhu, Chaoming Xie, Qiang Wei, Longquan Chen, Bo He, Hui Zhao, Yonghao Zheng, Deng Xu, Chen Wei, Dongsheng Wang Invisible inks have been applied for the secrecy of texts, symbols and binary images. Based on the photochromism of donor-acceptor Stenhouse adducts (DASAs) in the solid-state promoted by ester-contained molecules,... The content of this RSS Feed (c) The Royal Society of Chemistry
Source: RSC - Chem. Commun. latest articles - September 22, 2023 Category: Chemistry Authors: Fanxi Sun Source Type: research

Observation of An Electron-Precise Metal Boryne Complex: Bi ≡BHπΠ
This study uncovers a simple electron-precise metal boryne complex, [Bi ≡BH]−, which is produced within an ion trap through... The content of this RSS Feed (c) The Royal Society of Chemistry
Source: RSC - Chem. Commun. latest articles - September 22, 2023 Category: Chemistry Authors: Han-Wen Gao Source Type: research

In situ grown high-valence Mo-doped NiCo Prussian blue analogue for enhanced urea electrooxidation
Chem. Commun., 2023, Advance Article DOI: 10.1039/D3CC03790H, CommunicationXiaoxing Zhou, Jun Hu, Sara Ajmal, Dong Xiang, Zhenjie Sun, Wenxing Chen, Manzhou Zhu, Ping Chen, Peng Li A high-valence Mo6+-doped NiCo PBA with unique dual structures exhibited excellent preferences for the UOR and urea-assisted water electrolysis. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Source: RSC - Chem. Commun. latest articles - September 22, 2023 Category: Chemistry Authors: Xiaoxing Zhou Source Type: research

Ag(I)-Catalyzed Dearomatizing Spirocyclization/Nucleophile Addition Cascade Reactions of Indole-tethered Ynones
Chem. Commun., 2023, Accepted Manuscript DOI: 10.1039/D3CC03543C, CommunicationDebojyoti Bag, Sanghapal D. Sawant Ag(I)-catalyzed highly diastereoselective construction of divergent spiroindolines is disclosed herein. The approach proceeds via dearomatizing spirocyclization of indole-tethered ynones followed by C-nucleophile or hydride trapping. The established strategy is accompanied... The content of this RSS Feed (c) The Royal Society of Chemistry
Source: RSC - Chem. Commun. latest articles - September 22, 2023 Category: Chemistry Authors: Debojyoti Bag Source Type: research

BF3-Et2O Promoted Bifunctionalization of Aldehydes for the Synthesis of Arylmethyl Substituted Organophosphorus Compounds
Chem. Commun., 2023, Accepted Manuscript DOI: 10.1039/D3CC03898J, CommunicationSajjad Ahmed, Zoya Shafeeq, Feroze Hussain, Qazi Naveed Ahmed A simple and efficient protocol for the synthesis of arylmethyl substituted organophosphorus compounds is presented. This method involves the reaction of diphenyl phosphite with aldehydes in the presence of BF3-Et2O.... The content of this RSS Feed (c) The Royal Society of Chemistry
Source: RSC - Chem. Commun. latest articles - September 22, 2023 Category: Chemistry Authors: Sajjad Ahmed Source Type: research

Atomically dispersed Fe –O4–C sites as efficient electrocatalysts for electrosynthesis of hydrogen peroxide
Chem. Commun., 2023, Advance Article DOI: 10.1039/D3CC03969B, CommunicationLiuyue Cao, Hongrui Wang, Ningyan Cheng, Lei Zhang, Meiqing Shi, Bin-Wei Zhang The SA Fe/GO with Fe –O4–C active sites is developed as an efficient electrocatalyst to enhance the kinetics and selectivity towards the 2e ORR for the electrosynthesis of H2O2. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Source: RSC - Chem. Commun. latest articles - September 22, 2023 Category: Chemistry Authors: Liuyue Cao Source Type: research

Li+ mobility powered by a crystal compound for fast Li –S chemistry
Chem. Commun., 2023, Advance Article DOI: 10.1039/D3CC03535B, CommunicationBen Chen, Boxin Li, Jingxuan Bi, Hongfang Du, Siying Wang, Lei Liu, Linghai Xie, Jinmeng Sun, Zhuzhu Du, Wei Ai A Li-based crystal composited with carbon (LiPN2@C) has been synthesized by a one-step annealing of Li+ absorbed melamine polyphosphate, which presents strong LiPS adsorption and fast Li+ transport for a Li2S cathode. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Source: RSC - Chem. Commun. latest articles - September 22, 2023 Category: Chemistry Authors: Ben Chen Source Type: research

Constructing pyrene-based dimer in a crystal by adjusting steric hindrance over the pyrene plane
CrystEngComm, 2023, Accepted Manuscript DOI: 10.1039/D3CE00744H, PaperZhou-An Xia, Xiangyu Zhang, Chang Xi, Qing Bai, Haichao Liu, Shitong Zhang, Bing Yang Structure –property relationship is always a focus while organic light-emitting materials are used mainly in aggregate state in some fields, such as optoelectronic devices, sensors, and bioimaging. To clarify a clear... The content of this RSS Feed (c) The Royal Society of Chemistry
Source: RSC - CrystEngComm latest articles - September 22, 2023 Category: Chemistry Authors: Zhou-An Xia Source Type: research

Nanostructuring and stabilization of metastable rock-salt ZnO: Impact of high-pressure media and compression geometry
CrystEngComm, 2023, Accepted Manuscript DOI: 10.1039/D3CE00814B, PaperPetr S. Sokolov, Alexandre Courac, Vladimir L. Solozhenko For complete and reproducible recovery of a high-pressure polymorph of zinc oxide, rock-salt ZnO (rs-ZnO), nanostructured wurtzite ZnO (w-ZnO) is typically used as a precursor for high-pressure synthesis. In the... The content of this RSS Feed (c) The Royal Society of Chemistry
Source: RSC - CrystEngComm latest articles - September 22, 2023 Category: Chemistry Authors: Petr S. Sokolov Source Type: research

Fe-modulated NH2 –CoFe MOF nanosheet arrays on nickel foam by cation exchange reaction for an efficient OER electrocatalyst at high current density in alkaline water/seawater
CrystEngComm, 2023, Advance Article DOI: 10.1039/D3CE00728F, PaperDong Hyun Kim, Juyoung Moon, So Yeon Lee, Hyun Ji An, Hayeon Jeong, Jung Tae Park Preparation of NH2–CoFe MOF for the OER in alkaline water/seawater. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Source: RSC - CrystEngComm latest articles - September 22, 2023 Category: Chemistry Authors: Dong Hyun Kim Source Type: research

Quality consistency evaluation of chemical composition and pharmacology of Shaoyao-Gancao decoction dispensing granules and traditional decoction
This study presents a method for evaluating the quality consistency of DGCM and TD of SGD, offering novel insights into the evaluation of consistency between DGCM and TD.PMID:37736670 | DOI:10.1002/bmc.5745
Source: Biomedical Chromatography : BMC - September 22, 2023 Category: Biomedical Science Authors: Fengyu Dong Mengdi Xie Manwen Xu Lu Lu Yan Miao Panpan Zhang Xiaopeng Li Xinjing Gui Ruixin Liu Source Type: research

Pop-up screening nested within routine community activities unmasks an addressed cardiovascular risk: A pilot study (Gippsland Healthy Heart Study)
CONCLUSIONS: This study supported the feasibility and effectiveness of pop-up screening to detect CVRF in rural communities.PMID:37735862 | DOI:10.1111/ajr.13042
Source: The Australian Journal of Rural Health - September 22, 2023 Category: Rural Health Authors: Masashi Fujino Julie Butters Mark Boyes Noel Duncan Fleur Streets Amy Sabatini Alan Herschtal Adam J Nelson Stephen J Nicholls Source Type: research

Cytochrome P450 Mediated Cyclization in Eunicellane Derived Diterpenoid Biosynthesis
Angew Chem Int Ed Engl. 2023 Sep 21:e202312490. doi: 10.1002/anie.202312490. Online ahead of print.ABSTRACTTerpene cyclization, one of the most complex chemical reactions in nature, is generally catalyzed by two classes of terpene cyclases (TCs). Cytochrome P450s that act as unexpected TC-like enzymes are known but are very rare. Here, we genome-mined a cryptic bacterial terpenoid gene cluster, named ari, from the thermophilic actinomycete strain Amycolatopsis arida. By employing a heterologous production system, we isolated and characterized three highly oxidized eunicellane derived diterpenoids, aridacins A-C (1-3), that...
Source: Angewandte Chemie - September 22, 2023 Category: Chemistry Authors: Zengyuan Wang Qian Yang Jingyi He Haixin Li Xingming Pan Zining Li Hui-Min Xu Jeffrey Rudolf Dean Tantillo Liao-Bin Dong Source Type: research

Photocatalytic Free Radical-Controlled Synthesis of High-Performance Single-Atom Catalysts
In this study, we present a straightforward approach for preparing SACs utilizing a photocatalytic radical control strategy. Notably, we demonstrate for the first time that radicals generated during the photochemical process effectively hinder the aggregation of individual atoms. By leveraging the cooperative anchoring of nitrogen atoms and crystal lattice oxygen on the support, we successfully stabilize the single atom. Our Pd1/TiO2 catalysts exhibit remarkable catalytic activity and stability in the Suzuki-Miyaura cross-coupling reaction, which was 43 times higher than Pd/C. Furthermore, we successfully depose Pd atoms o...
Source: Angewandte Chemie - September 22, 2023 Category: Chemistry Authors: Xiang Chen Shuhui Guan Jianjiang Zhou Hengjun Shang Jingyuan Zhang Fujian Lv Han Yu Hexing Li Zhenfeng Bian Source Type: research