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Mechanistic insights into trisulfur radical generation in lithium –sulfur batteries
J. Mater. Chem. A, 2023, Advance Article DOI: 10.1039/D3TA03366J, PaperXu Han, Xuefei Xu Trisulfur radicals ( and) are more favorable to be generated by hexasulfides (Li2S6, LiS6−, and S62 −) when the solvent has a higher donor number and dielectric constant, and the hexasulfides are more fully solvated. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Source: RSC - J. Mater. Chem. latest articles - August 23, 2023 Category: Chemistry Authors: Xu Han Source Type: research
A Freestanding 3D Skeleton with Gradationally Distributed Lithiophilic Sites for Realizing Stable Lithium Anodes
Chemistry. 2023 Aug 23:e202301991. doi: 10.1002/chem.202301991. Online ahead of print.ABSTRACTLi metal anodes are drawing considerable attention owing to their ultrahigh theoretical capacities and low electrochemical reduction potentials. However, their commercialization has been hampered by safety hazards induced by continuous dendrite growth. These issues can be alleviated using the ZnO-modified 3D carbon-based host containing carbon nanotubes (CNTs) and carbon felt (CF) fabricated by electroplating in the present study (denoted as ZnO/CNT@CF); the constructed skeleton has lithiophilic ZnO that is gradationally distribut...
Source: Chemistry - August 23, 2023 Category: Chemistry Authors: Tianhui Li Hanxiao Zhou Wenjing Liu Jingjing Gao Zhihao Guo Zihao Su Yuanting Yan Shaoxiang Su Haoyu Xie Gongchang Peng Meizhen Qu Source Type: research
Integrated recycling of valuable elements from spent LiFePO4 batteries: a green closed-loop process
Green Chem., 2023, Accepted Manuscript DOI: 10.1039/D3GC02180G, PaperHuixiang Zhou, Yun Zhang, Liqing Li, Zhanfang Cao The harmless disposal and resourceful recovery of spent lithium-ion batteries is an inevitable choice to protect the environment, conserve resources and promote the development of the circular economy. A systematic,... The content of this RSS Feed (c) The Royal Society of Chemistry
Source: RSC - Green Chem. latest articles - August 23, 2023 Category: Chemistry Authors: Huixiang Zhou Source Type: research
Confinement-enhanced Li+ ion dynamics in an ionic liquid-based electrolyte in porous material
Phys. Chem. Chem. Phys., 2023, Accepted Manuscript DOI: 10.1039/D3CP02901H, PaperJanis Hessling, Martin Lange, Monika Sch önhoff While Ionic Liquids (IL) are promising liquid electrolyte components for Li-ion batteries due to their high electrochemical stability and low volatility and flammability, unfavorable Lithium-anion clusters lead to poor Li+... The content of this RSS Feed (c) The Royal Society of Chemistry
Source: RSC - Phys. Chem. Chem. Phys. latest articles - August 22, 2023 Category: Chemistry Authors: Janis Hessling Source Type: research
P-doping boosting electronic properties and ionic kinetics of MnV2O6 for high-performance lithium-ion batteries
Dalton Trans., 2023, Accepted Manuscript DOI: 10.1039/D3DT02292G, PaperZheng Wu, Lang Zhang, Sui Peng, Dong Fang, Jianhong Yi High-energy density vanadate electrode materials of rechargeable lithium-ion batteries (LIBs) have reserved widespread concerns for utilizing sustainable and clean energy. However, their practical application suffers from the limitation of poor... The content of this RSS Feed (c) The Royal Society of Chemistry
Source: RSC - Dalton Trans. latest articles - August 22, 2023 Category: Chemistry Authors: Zheng Wu Source Type: research
Development of Membranes and Separators to Inhibit Cross-Shuttling of Sulfur in Polysulfide-Based Redox Flow Batteries: A Review
Chem Rec. 2023 Aug 22:e202300171. doi: 10.1002/tcr.202300171. Online ahead of print.ABSTRACTThe global rapid transition from fossil fuels to renewable energy resources necessitates the implementation of long-duration energy storage technologies owing to the intermittent nature of renewable energy sources. Therefore, the deployment of grid-scale energy storage systems is inevitable. Sulfur-based batteries can be exploited as excellent energy storage devices owing to their intrinsic safety, low cost of raw materials, low risk of environmental hazards, and highest theoretical capacities (gravimetric: 2600 Wh/kg and volumetric...
Source: Chemical Record - August 22, 2023 Category: Chemistry Authors: Ibad Ali Khan Atif Saeed Alzahrani Shahid Ali Muhammad Mansha Muhammad Nawaz Tahir Majad Khan Hafiz Adil Qayyum Safyan Akram Khan Source Type: research
Evaluating a Dual-Ion Battery with an Antimony-Carbon Composite Anode
ChemSusChem. 2023 Aug 22:e202300445. doi: 10.1002/cssc.202300445. Online ahead of print.ABSTRACTDual-ion batteries (DIBs) are attracting attention due to their high operating voltage and promise in stationary energy storage applications. Among various anode materials, elements that alloy and dealloy with lithium are assumed to be prospective in bringing higher capacities and increasing the energy density of DIBs. In this work, antimony in the form of a composite with carbon (Sb-C) is evaluated as an anode material for DIB full cells for the first time. The behaviour of graphite||Sb-C cells is assessed in highly concentrate...
Source: ChemSusChem - August 22, 2023 Category: Chemistry Authors: Thrinathreddy Ramireddy Jens Matthies Wrogemann Lukas Haneke Irin Sultana Felipe Kremer Ying Ian Chen Martin Winter Tobias Placke Alexey M Glushenkov Source Type: research
Development of Membranes and Separators to Inhibit Cross-Shuttling of Sulfur in Polysulfide-Based Redox Flow Batteries: A Review
Chem Rec. 2023 Aug 22:e202300171. doi: 10.1002/tcr.202300171. Online ahead of print.ABSTRACTThe global rapid transition from fossil fuels to renewable energy resources necessitates the implementation of long-duration energy storage technologies owing to the intermittent nature of renewable energy sources. Therefore, the deployment of grid-scale energy storage systems is inevitable. Sulfur-based batteries can be exploited as excellent energy storage devices owing to their intrinsic safety, low cost of raw materials, low risk of environmental hazards, and highest theoretical capacities (gravimetric: 2600 Wh/kg and volumetric...
Source: Chemical Record - August 22, 2023 Category: Chemistry Authors: Ibad Ali Khan Atif Saeed Alzahrani Shahid Ali Muhammad Mansha Muhammad Nawaz Tahir Majad Khan Hafiz Adil Qayyum Safyan Akram Khan Source Type: research
Directing (110) Oriented Lithium Deposition through High-flux Solid Electrolyte Interphase for Dendrite-free Lithium Metal Batteries
Angew Chem Int Ed Engl. 2023 Aug 22:e202309622. doi: 10.1002/anie.202309622. Online ahead of print.ABSTRACTControlling lithium (Li) electrocrystallization with preferred orientation is a promising strategy to realize highly reversible Li metal batteries (LMBs) but lack of facile regulation methods. Herein, we report a high-flux solid electrolyte interphase (SEI) strategy to direct (110) preferred Li deposition even on (200)-orientated Li substrate. Bravais rule and Curie-Wulff principle are expanded in Li electrocrystallization process to decouple the relationship between SEI engineering and preferred crystal orientation. ...
Source: Angewandte Chemie - August 22, 2023 Category: Chemistry Authors: Zehui Sun Yuankun Wang Shenyu Shen Xinyang Li Xiaofei Hu Mingyou Hu Yaqiong Su Chunhui Xiao Shujiang Ding Source Type: research
Development of Membranes and Separators to Inhibit Cross-Shuttling of Sulfur in Polysulfide-Based Redox Flow Batteries: A Review
Chem Rec. 2023 Aug 22:e202300171. doi: 10.1002/tcr.202300171. Online ahead of print.ABSTRACTThe global rapid transition from fossil fuels to renewable energy resources necessitates the implementation of long-duration energy storage technologies owing to the intermittent nature of renewable energy sources. Therefore, the deployment of grid-scale energy storage systems is inevitable. Sulfur-based batteries can be exploited as excellent energy storage devices owing to their intrinsic safety, low cost of raw materials, low risk of environmental hazards, and highest theoretical capacities (gravimetric: 2600 Wh/kg and volumetric...
Source: Chemical Record - August 22, 2023 Category: Chemistry Authors: Ibad Ali Khan Atif Saeed Alzahrani Shahid Ali Muhammad Mansha Muhammad Nawaz Tahir Majad Khan Hafiz Adil Qayyum Safyan Akram Khan Source Type: research
Recycle graphite from spent lithium-ion batteries for H < sub > 2 < /sub > O < sub > 2 < /sub > electrosynthesis
Environ Sci Pollut Res Int. 2023 Aug 22. doi: 10.1007/s11356-023-29354-3. Online ahead of print.ABSTRACTOn-site H2O2 synthesis via the two-electron route oxygen reduction reaction for environmental remediation is attractive. This work offers a novel strategy for both spent graphite recovery and H2O2 electrosynthesis catalyst preparation. The graphite is directly recycled from spent lithium-ion batteries to an H2O2 electrosynthesis catalyst. From the view of sustainable development and environmental protection, the H2O2 electrosynthesis catalyst prepared using spent graphite is eco-friendly and cost-efficient. The surface f...
Source: Environmental Science and Pollution Research International - August 22, 2023 Category: Environmental Health Authors: Jucai Wei Xi Wang Xu Wu Source Type: research
Development of Membranes and Separators to Inhibit Cross-Shuttling of Sulfur in Polysulfide-Based Redox Flow Batteries: A Review
Chem Rec. 2023 Aug 22:e202300171. doi: 10.1002/tcr.202300171. Online ahead of print.ABSTRACTThe global rapid transition from fossil fuels to renewable energy resources necessitates the implementation of long-duration energy storage technologies owing to the intermittent nature of renewable energy sources. Therefore, the deployment of grid-scale energy storage systems is inevitable. Sulfur-based batteries can be exploited as excellent energy storage devices owing to their intrinsic safety, low cost of raw materials, low risk of environmental hazards, and highest theoretical capacities (gravimetric: 2600 Wh/kg and volumetric...
Source: Chemical Record - August 22, 2023 Category: Chemistry Authors: Ibad Ali Khan Atif Saeed Alzahrani Shahid Ali Muhammad Mansha Muhammad Nawaz Tahir Majad Khan Hafiz Adil Qayyum Safyan Akram Khan Source Type: research
The effects of defects on the transport mechanisms of lithium ions in organic ionic plastic crystals
Phys. Chem. Chem. Phys., 2023, Advance Article DOI: 10.1039/D3CP02088F, PaperHyungshick Park, Chung Bin Park, Bong June Sung Defects such as grain boundaries alter the structure of ions and cause the non-Gaussian heterogenous dynamics of ions in OIPCs. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Source: RSC - Phys. Chem. Chem. Phys. latest articles - August 21, 2023 Category: Chemistry Authors: Hyungshick Park Source Type: research
Exploring the impact of lithium halide-based redox mediators in suppressing CO2 evolution in Li –O2 cells
This article is licensed under aCreative Commons Attribution 3.0 Unported Licence.Sri Harsha Akella, Muniyandi Bagavathi, Rosy, Daniel Sharon, Capraz Ozgur, Malachi Noked The graphical abstract depicts that the Li –O2 cell failure is directly proportional to CO2 evolution. Cells containing optimal LiBr as redox mediator has significantly suppressed the CO2 evolution upon prolonged Li –O2 cycling. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Source: RSC - J. Mater. Chem. latest articles - August 21, 2023 Category: Chemistry Authors: Sri Harsha Akella Source Type: research
