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A high-performance TPGDA/PETEA composite gel polymer electrolyte for lithium metal batteries
Chem. Commun., 2023, Advance Article DOI: 10.1039/D3CC02598E, CommunicationZhifu Chen, Quan Pei, Zhitao An, Yiting Tong, Qingfeng Zhang, Shuhong Xie A gel electrolyte formed byin situ polymerization of a precursor solution with TPGDA and PETEA monomers on a PI membrane containing LLZTO particles, is found to exhibit excellent electrochemical performance. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Source: RSC - Chem. Commun. latest articles - August 9, 2023 Category: Chemistry Authors: Zhifu Chen Source Type: research
Lithium polyacrylate as lithium and carbon source in the synthesis of Li3VO4for high-rate and long-life Li-ion batteries
ChemSusChem. 2023 Aug 9:e202300979. doi: 10.1002/cssc.202300979. Online ahead of print.ABSTRACTLi3VO4 is a promising anode material for use in lithium-ion batteries, however, the conventional synthesis methods for Li3VO4 anodes involve the separate use of lithium and carbon sources, resulting in inefficient contact and low crystalline quality. Herein, we utilized lithium polyacrylate (LiPAA) as a dual-functional source and employed an in-situ polymerization followed by a spray-drying method to synthesize Li3VO4. LiPAA serves a dual purpose, acting as both a lithium source to improve the crystal process and a carbon source ...
Source: ChemSusChem - August 9, 2023 Category: Chemistry Authors: Haokun Yan Cunyuan Pei Yan Zhang Yiwei Zhao Xun Chen Zongping Zhang Dongmei Zhang Bing Sun Huijuan Ma Shibing Ni Source Type: research
Sulfur-Decorated Ti < sub > 3 < /sub > C < sub > 2 < /sub > T < sub > X < /sub > MXene for High-Performance Sodium/Potassium-Ion Batteries
Chem Asian J. 2023 Aug 9:e202300336. doi: 10.1002/asia.202300336. Online ahead of print.ABSTRACTAs post-lithium ion batteries, both sodium-ion batteries (SIBs) and potassium ion batteries (PIBs) possess great potential for large scale energy storage. However, the application of both SIBs and PIBs are hindered by the lack of suitable electrode materials. Here, we synthesized the sulfur decorated Ti3 C2 Tx (S-T3 C2 Tx ) MXene as electrode material for SIBs and PIBs. Thanks to the sulfur functional group and the formation of Ti-S bond, which facilitates the sodium in-/desertion and strengthens the potassium ion adsorption abi...
Source: Chemistry, an Asian Journal - August 9, 2023 Category: Chemistry Authors: Zhendong Guo Guangsheng Dong Man Zhang Musen Gao Leijun Shao Meng Chen Hongli Liu Mingchen Ni Dianxue Cao Kai Zhu Source Type: research
A high-performance TPGDA/PETEA composite gel polymer electrolyte for lithium metal batteries
Chem Commun (Camb). 2023 Aug 9. doi: 10.1039/d3cc02598e. Online ahead of print.ABSTRACTA gel polymer electrolyte (GPE) supported by a polyimide (PI) nanofiber membrane with Li6.5La3Zr1.5Ta0.5O12 (LLZTO) nanoparticles (PI/LLZTO/GPE) shows excellent flexibility and electrochemical properties, the ionic conductivity is 1.87 mS cm-1 and the Li+ transfer number is 0.64 at room temperature. The assembled Li metal battery with a LiFePO4 (LFP) cathode retains a 56.4 mA h g-1 discharge capacity at 10C.PMID:37554079 | DOI:10.1039/d3cc02598e
Source: Chemical Communications - August 9, 2023 Category: Chemistry Authors: Zhifu Chen Quan Pei Zhitao An Yiting Tong Qingfeng Zhang Shuhong Xie Source Type: research
Lithium polyacrylate as lithium and carbon source in the synthesis of Li3VO4for high-rate and long-life Li-ion batteries
ChemSusChem. 2023 Aug 9:e202300979. doi: 10.1002/cssc.202300979. Online ahead of print.ABSTRACTLi3VO4 is a promising anode material for use in lithium-ion batteries, however, the conventional synthesis methods for Li3VO4 anodes involve the separate use of lithium and carbon sources, resulting in inefficient contact and low crystalline quality. Herein, we utilized lithium polyacrylate (LiPAA) as a dual-functional source and employed an in-situ polymerization followed by a spray-drying method to synthesize Li3VO4. LiPAA serves a dual purpose, acting as both a lithium source to improve the crystal process and a carbon source ...
Source: ChemSusChem - August 9, 2023 Category: Chemistry Authors: Haokun Yan Cunyuan Pei Yan Zhang Yiwei Zhao Xun Chen Zongping Zhang Dongmei Zhang Bing Sun Huijuan Ma Shibing Ni Source Type: research
An Increase in Peroxiredoxin 6 Expression Induces Neurotoxic A1 Astrocytes in the Lumbar Spinal Cord of Amyotrophic Lateral Sclerosis Mice Model
In this study, we observed that the expression of peroxiredoxin 6 (PRDX6), a member of the peroxiredoxin family, was markedly upregulated in astrocytes of the lumbar spinal cord of SOD1G93A mice model for ALS. Additionally, when PRDX6 was transiently transfected into the mouse astrocyte cell line C8-D1A and human astrocytoma cell line U-251 MG, the mRNA expression of complement C3 (a marker for A1 astrocyte phenotype) and inflammatory cytokines was increased. Furthermore, the mRNA expression of C3 and inflammatory cytokine was increased in C8-D1A and U-251 MG cells stably expressing PRDX6, and the increased mRNA expression...
Source: Neurochemical Research - August 9, 2023 Category: Neuroscience Authors: Akiko Yamamuro-Tanabe Yurika Mukai Wataru Kojima Siyuan Zheng Naoko Matsumoto Shoho Takada Mao Mizuhara Yasuhiro Kosuge Yuki Ishimaru Yasuhiro Yoshioka Source Type: research
Sulfur-Decorated Ti < sub > 3 < /sub > C < sub > 2 < /sub > T < sub > X < /sub > MXene for High-Performance Sodium/Potassium-Ion Batteries
Chem Asian J. 2023 Aug 9:e202300336. doi: 10.1002/asia.202300336. Online ahead of print.ABSTRACTAs post-lithium ion batteries, both sodium-ion batteries (SIBs) and potassium ion batteries (PIBs) possess great potential for large scale energy storage. However, the application of both SIBs and PIBs are hindered by the lack of suitable electrode materials. Here, we synthesized the sulfur decorated Ti3 C2 Tx (S-T3 C2 Tx ) MXene as electrode material for SIBs and PIBs. Thanks to the sulfur functional group and the formation of Ti-S bond, which facilitates the sodium in-/desertion and strengthens the potassium ion adsorption abi...
Source: Chemistry, an Asian Journal - August 9, 2023 Category: Chemistry Authors: Zhendong Guo Guangsheng Dong Man Zhang Musen Gao Leijun Shao Meng Chen Hongli Liu Mingchen Ni Dianxue Cao Kai Zhu Source Type: research
An Increase in Peroxiredoxin 6 Expression Induces Neurotoxic A1 Astrocytes in the Lumbar Spinal Cord of Amyotrophic Lateral Sclerosis Mice Model
In this study, we observed that the expression of peroxiredoxin 6 (PRDX6), a member of the peroxiredoxin family, was markedly upregulated in astrocytes of the lumbar spinal cord of SOD1G93A mice model for ALS. Additionally, when PRDX6 was transiently transfected into the mouse astrocyte cell line C8-D1A and human astrocytoma cell line U-251 MG, the mRNA expression of complement C3 (a marker for A1 astrocyte phenotype) and inflammatory cytokines was increased. Furthermore, the mRNA expression of C3 and inflammatory cytokine was increased in C8-D1A and U-251 MG cells stably expressing PRDX6, and the increased mRNA expression...
Source: Cell Research - August 9, 2023 Category: Cytology Authors: Akiko Yamamuro-Tanabe Yurika Mukai Wataru Kojima Siyuan Zheng Naoko Matsumoto Shoho Takada Mao Mizuhara Yasuhiro Kosuge Yuki Ishimaru Yasuhiro Yoshioka Source Type: research
Understanding of Stress-Driven Internal Short Circuit Mechanisms in Lithium-Ion Batteries with High SOCs
In this study, combined post-mortem characterization and multiphysics modeling is employed to clarify the evolution of ISC modes in LIBs with high SOCs. These findings reveal that the triggered ISC mode is SOC-dependent, with the Al current collector (Al)-Anode coating (An) mode dominant in high SOC situations. Experimentally obtained ISC resistance for the specified ISC mode is then assigned to the corresponding ISC region in the established multiphysics model, allowing for accurate coupling of the electromechanical relationship and prediction of mechanical-electrical-thermal responses of the LIB. Finally, a simple yet ef...
Source: Adv Data - August 9, 2023 Category: Epidemiology Authors: Xudong Duan Jiani Li Yikai Jia Xiang Gao Lubing Wang Jun Xu Source Type: research
Hybrid Sub-1 nm Nanosheets of Co-assembled MnZnCuOx and Polyoxometalate Clusters as Anodes for Li-ion Batteries
Angew Chem Int Ed Engl. 2023 Aug 8:e202309934. doi: 10.1002/anie.202309934. Online ahead of print.ABSTRACTHybrid Sub-1 nm Nanosheets of Co-assembled MnZnCuOx and Polyoxometalate Clusters as Anodes for Li-ion BatteriesTransition metal oxide (TMO) anode materials in lithium-ion batteries (LIBs) usually suffer from serious volume expansion leading to the pulverization of structures, further giving rise to lower specific capacity and worse cycling stability. Herein, by introducing polyoxometalate (POM) clusters into TMOs and precisely controlling the amount of POMs, the MnZnCuOx-phosphomolybdic acid hybrid sub-1 nm nanosheets ...
Source: Angewandte Chemie - August 8, 2023 Category: Chemistry Authors: Guobao Yuan Huaiyun Ge Wenxiong Shi Junli Liu Yu Zhang Xun Wang Source Type: research
Ammonium fluoride induced barrier-free and oxygen vacancies enhanced LLZO powder for fast interfacial lithium-ion transport in composite solid electrolytes
J. Mater. Chem. A, 2023, Accepted Manuscript DOI: 10.1039/D3TA03195K, PaperZiwen Pan, Shiyu Cao, Xinqi Lu, Gang Zhang, Qiang Shen, Chong Mao, Xiaobing Dai, Fei Chen The interphase structure and Li-ion transport across interface are essential for high-performance composite solid electrolytes (CPEs). Tailoring the interface between rigid inorganic solid electrolyte fillers and polymer electrolyte matrix is... The content of this RSS Feed (c) The Royal Society of Chemistry
Source: RSC - J. Mater. Chem. latest articles - August 7, 2023 Category: Chemistry Authors: Ziwen Pan Source Type: research
Lithium isotope tracing in silicon based electrodes using solid-state MAS NMR: a powerful comprehensive tool for the characterization of lithium battery
This article is licensed under aCreative Commons Attribution-NonCommercial 3.0 Unported Licence.Manon Berthault, Anton Buzlukov, Lionel Dubois, Pierre-Alain Bayle, Willy Porcher, Thibaut Gutel, Eric De Vito, Michel Bardet The introduction of lithiated components with different 7Li/6Li isotopic ratio, also called isotopic tracing, can give access to better understanding of the lithium transport and lithiation processes in lithium-ion batteries.... The content of this RSS Feed (c) The Royal Society of Chemistry
Source: RSC - Phys. Chem. Chem. Phys. latest articles - August 7, 2023 Category: Chemistry Authors: Manon Berthault Source Type: research
Modelling Electro-Chemically Induced Stresses in All-Solid-State Batteries: Screening Electrolyte and Cathode Materials in Composite Cathodes
This article is licensed under aCreative Commons Attribution 3.0 Unported Licence.Robert M ücke, Najma Yaqoob, Martin Finsterbusch, Fadi Al-Jaljouli, Payam Kaghazchi, Dina Fattakhova-Rohlfing, Olivier Guillon All-solid-state lithium batteries (ASSBs) are gaining significant attention worldwide as one of the most promising alternatives to lithium-ion batteries due to their superior safety and potentially higher energy density. However,... The content of this RSS Feed (c) The Royal Society of Chemistry
Source: RSC - J. Mater. Chem. latest articles - August 7, 2023 Category: Chemistry Authors: Robert M ücke Source Type: research
