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The chemical synthesis and anti-cancer properties of portimines
Nature, Published online: 20 September 2023; doi:10.1038/d41586-023-02788-yThe natural toxins portimine A and B have attracted interest for their unusual chemical architecture and potent anti-cancer activity. The first total synthesis of portimines enables the identification of portimine A’s molecular target and reveals that the toxin induces programmed cell death in human cancer cells.
Source: Nature AOP - September 20, 2023 Category: Research Source Type: research

Controlling emission energy in metal & #x2013;organic frameworks featuring cyclometalated iridium(III) linkers
Carol Hua, Timothy U. Connell Diagram of iridium and metalloligands combining with Ca2+; graph of resulting metal–organic framework luminescence peakThree iridium(III) metalloligands containing different cyclometallating ligands were incorporated into Ca2+ metal–organic frameworks yielding luminescent materials. Changing the cyclometalling ligand altered the emission wavelength, highlighting the utility of this approach for the generation of tailored solid-state materials for applications including chemical sensing. (Image credit: C. Hua and T. U. Connell.)
Source: Australian Journal of Chemistry - September 20, 2023 Category: Chemistry Authors: Carol Hua Timothy U. Connell Source Type: research

Cycle Syncing Won ’ t Fix Women ’ s Fitness
While most of the video series and programs available on the popular “holistic wellness”/fitness site Alo Moves—owned by the trendy activewear line Alo Yoga—are run by solitary instructors, the company’s newest offering is marked by photos and videos of a group of four women pulled close up against one another and roaming Hawaiian beaches. It’s a clearly symbolic presentation of the company’s new SYNCD program, a collection of 24 videos designed to guide users through self-care and fitness activities customized for each of the four phases of the menstrual cycle. The program, whi...
Source: TIME: Health - September 19, 2023 Category: Consumer Health News Authors: Haley Weiss Tags: Uncategorized healthscienceclimate Source Type: news

Model calculations for the prediction of the diradical character of physisorbed molecules: p-Benzyne/MgO and p-Benzyne/SrO
Phys. Chem. Chem. Phys., 2023, Accepted Manuscript DOI: 10.1039/D3CP02988C, PaperKohei Tada, Takashi Kawakami, Yoyo Hinuma The analysis of the diradical state of functional open-shell molecules is important for understanding their physical properties and chemical reactivity. The diradical character is an important factor in the functional... The content of this RSS Feed (c) The Royal Society of Chemistry
Source: RSC - Phys. Chem. Chem. Phys. latest articles - September 19, 2023 Category: Chemistry Authors: Kohei Tada Source Type: research

Speciation of potential-dependent fouling on copper foil electrodes during electrochemical hydrogenation and hydrogenolysis of furfural in strong acid
Green Chem., 2023, Accepted Manuscript DOI: 10.1039/D3GC02222F, PaperAndrew S. May, Elizabeth J. Biddinger The electrochemical transformation of sustainable feedstocks such as biomass derived species can help to electrify the chemical industry and reduce reliance on petroleum. Furfural (FF), one such biomass derived species,... The content of this RSS Feed (c) The Royal Society of Chemistry
Source: RSC - Green Chem. latest articles - September 19, 2023 Category: Chemistry Authors: Andrew S. May Source Type: research

Synergizing Mitigated Spatial Confinement and Chemical Stabilization of Lignin Facilitates Full Utilization of Lignocellulose
Green Chem., 2023, Accepted Manuscript DOI: 10.1039/D3GC02826G, PaperJiayi Zheng, Liheng Chen, Xueqing Qiu, Shirong Sun, Xuliang Lin Condensation, dark color and low extraction yield of lignin have hindered the full valorization of biomass during lignocellulosic fractionation. Herein, we introduce a novel biomass fractionation concept that addresses the... The content of this RSS Feed (c) The Royal Society of Chemistry
Source: RSC - Green Chem. latest articles - September 19, 2023 Category: Chemistry Authors: Jiayi Zheng Source Type: research

Surface-modified bacteria: synthesis, functionalization and biomedical applications
Chem. Soc. Rev., 2023, Advance Article DOI: 10.1039/D3CS00369H, Tutorial ReviewSisi Lin, Feng Wu, Yifan Zhang, Huan Chen, Haiyan Guo, Yanmei Chen, Jinyao Liu This review summarizes the strategies for surface chemical modification of bacteria and advanced functions achieved by modifying specific surface components and highlights the applications of modified bacteria for bioimaging, diagnosis, and therapy. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Source: RSC - Chemical Society Reviews - September 19, 2023 Category: Chemistry Authors: Sisi Lin Source Type: research

QSPR models to predict the physical hazards of mixtures: a state of art - Fayet G, Rotureau P.
Physical hazards of chemical mixtures, associated for example with their fire or explosion risks, are generally characterized using experimental tools. These tests can be expensive, complex, long to perform and even dangerous for operators. Therefore, for ...
Source: SafetyLit - September 19, 2023 Category: International Medicine & Public Health Tags: Burns, Electricity, Explosions, Fire, Scalds Source Type: news

60% Of Sun Screens Would Fail Federal Safety Tests!
Here in South Florida, spring break is in full swing. Temperatures are in the mid-to-high-80s, and tourists are flocking to our beautiful, sunny beaches. Of course, that also means it’s prime time for sunscreen companies to kick up their marketing efforts in an attempt to whip up more fear over the sun. They want to scare you into thinking that each time the sun strikes your unprotected skin, you risk malignant melanoma, the deadliest form of skin cancer. If you’re a regular reader, you know that I’ve been vocal about Big Retail’s money grab and how they put out misinformation because they profit each time you slat...
Source: Al Sears, MD Natural Remedies - September 19, 2023 Category: Complementary Medicine Authors: Jacob Tags: Anti-Aging Source Type: news

How To Avoid China ’ s Medicine Monopoly
I want to share a shocking statistic with you… Around 80% of all the pharmaceuticals sold in America — both prescription and over-the-counter — are manufactured in China. I’m talking about drugs for Parkinson’s and Alzheimer’s, blood pressure and blood thinners, diuretics, aspirin, antibiotics, and a big chunk of the world’s insulin and diabetes drugs — just to name a few.1 We don’t even make penicillin anymore. The last penicillin plant in the U.S. closed its doors in 2004. Americans who rely on medicine are now almost entirely at the mercy of a country whose relations with the U.S. have become more ...
Source: Al Sears, MD Natural Remedies - September 19, 2023 Category: Complementary Medicine Authors: Jacob Tags: Health Source Type: news

Why Diabetes Risk Is Higher For Older White Women
Phthalates – the toxic chemical cocktail manufacturers use to make plastic products more durable and personal products smell better – can increase your risk of developing diabetes by up to 63%… That’s the terrifying conclusion of a new study published in the Journal of Clinical Endocrinology & Metabolism.1 And according to the researchers, the damaging effects extend beyond diabetes in these women. Phthalate exposure also contributed to a higher incidence of obesity, infertility, and other endocrine disorders over a six-year period. For reasons not yet understood by the scientists, this damaging associatio...
Source: Al Sears, MD Natural Remedies - September 19, 2023 Category: Complementary Medicine Authors: Jacob Tags: Anti-Aging Nutrition Source Type: news

Cayman Chemical Receives CEP for Latanoprost API from EDQM
Cayman Chemical, a world leader in the manufacture of prostaglandins for both research use and as active pharmaceutical ingredients (APIs), has been granted a CEP for its latanoprost API. Cayman Chemical is the first company in the USA to receive a CEP for latanoprost. ANN ARBOR, Mich.,...
Source: PRWeb: Medical Pharmaceuticals - September 19, 2023 Category: Pharmaceuticals Source Type: news

Enhanced ORR Performance to Electrochemical Lignin Valorization in a Mixture Ionic Liquid/ Organic Solvent Binary Electrolyte
New J. Chem., 2023, Accepted Manuscript DOI: 10.1039/D3NJ03967F, PaperHaomin Jiang, Ang Li, Yanzhi Sun, Lei Wang, Yongmei Chen Lignin is the largest renewable source of aromatic compounds, creating an opportunity for chemical industry as a feedstock provided that the deconstruction and upgrading methods become economically feasible. Lignin valorization... The content of this RSS Feed (c) The Royal Society of Chemistry
Source: RSC - New J. Chem. latest articles - September 19, 2023 Category: Chemistry Authors: Haomin Jiang Source Type: research

Quantitative prediction of the solvent fractionation of lignin
This article is licensed under aCreative Commons Attribution 3.0 Unported Licence.Stijn H. M. van Leuken, Dannie J. G. P. van Osch, Panos D. Kouris, Yawen Yao, Monika A. Jedrzejczyk, Geert J. W. Cremers, Katrien V. Bernaerts, Rolf A. T. M. van Benthem, Remco Tuinier, Michael D. Boot, Emiel J. M. Hensen, Mark Vis A combined experimental and theoretical framework was developed that predicts the solvent fractionation of lignin, taking chemical and physical dispersity into account. This paves the way for a broader applicability of lignin in bio-based materials. To cite this article before page numbers are assigned, use the DOI...
Source: RSC - Green Chem. latest articles - September 19, 2023 Category: Chemistry Authors: Stijn H. M. van Leuken Source Type: research

Formation and sedimentation of oil-mineral aggregates in the presence of chemical dispersant
Environ. Sci.: Processes Impacts, 2023, Accepted Manuscript DOI: 10.1039/D3EM00327B, PaperWenxin Li, Zhixin Qi, Deqi Xiong, Yifei Wu, Wei Wang, Yajing Qi, Jian Guo The formation and sedimentation of oil-mineral aggregates (OMA) is the major transport way of the spilled oil to the seafloor. In this paper, the formation and sedimentation experiments of OMA... The content of this RSS Feed (c) The Royal Society of Chemistry
Source: RSC - J. Environ. Monit. latest articles - September 19, 2023 Category: Environmental Health Authors: Wenxin Li Source Type: research